Stability, spectra and structure of complexes of Pd (II) and Pt(II) with dithiooxamide immobilized on the SiO_2 surface

Yatsimirskii K.B.; Belyakova L.A.; Kravchenko O.V.

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Stability, spectra and structure of complexes of Pd (II) and Pt(II) with dithiooxamide immobilized on the SiO_2 surface

机译：Pd（II）和Pt（II）与固定在SiO_2表面的二硫代草酰胺的配合物的稳定性，光谱和结构

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It has been shown, that bonding Pd(II) and Pt(II) by immobilized on the SiO_2 surfice dithiooxamide with chloride aquous solutions is realized by means of complexation with Pd(II) and Pt(II). Electron and IR-spectra of obtained complexes are given. Immobilized dithiooxamide has arch structure and is being deformed in the process of complexation. The meaning of effective constants of Pd(II) and Pt(II) sorbtion has been obtained and they indicate more strong bonding of Pt(II) in comparison with Pd(II).

机译：已经表明，通过与Pd（II）和Pt（II）的络合，通过将Pd（II）和Pt（II）固定在具有氯化物水溶液的SiO 2表面二硫代乙酰胺上而实现。给出了所得配合物的电子和红外光谱。固定的二硫代草酰胺具有弓形结构，并且在络合过程中会变形。已经获得了Pd（II）和Pt（II）吸附有效常数的含义，并且它们表明与Pd（II）相比，Pt（II）的结合更牢固。

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《Украинский химический журнал》 |1999年第8期|p.77-82|共6页
作者
Yatsimirskii K.B.; Belyakova L.A.; Kravchenko O.V.;
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收录信息美国《科学引文索引》(SCI);
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正文语种 rus
中图分类化学;
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Stability, spectra and structure of complexes of Pd (II) and Pt(II) with dithiooxamide immobilized on the SiO_2 surface

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