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Synthesis and physicochemical properties of aniline-naphthylamine sulfonic acid copolymers

机译:苯胺-萘胺磺酸共聚物的合成及理化性质

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摘要

The physico-chemical properties of conducting copolymers of aniline and isomeric 1,8-,1,4-, 1,5-aminonaphthalene sulfonic acid obtained by oxidative polymerization in sulfuric acid water solution have been investigated by IR-, UV-, EPR-spectroscopy. It was found that obtained products are characterized by high thermal stability and paramagnetic susceptibility as compared with polyaniline synthesized in the same conditions. The possible mechanism of polyadition reactions are proposed.
机译:通过IR-,UV-,EPR-研究了苯胺与异构体1,8-,1,4-,1,5-氨基萘磺酸在硫酸水溶液中氧化聚合得到的导电共聚物的理化性质。光谱学。发现与在相同条件下合成的聚苯胺相比,获得的产物具有高的热稳定性和顺磁敏感性。提出了多加成反应的可能机理。

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