A study of the interaction of dicthylenetriamine complexes of copper fixed on silica with reagents of different nature by the eSR method

Zaitsev V.N.; Volkov A.N.; Zub V.Y.

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A study of the interaction of dicthylenetriamine complexes of copper fixed on silica with reagents of different nature by the eSR method

机译：eSR法研究固定在二氧化硅上的铜的二亚乙基三胺配合物与不同性质的试剂的相互作用

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The interactions between 22 organic and inorganic compounds of different nature with copper (II)-diethilentriamine complexes, covalently bonded to silica, were studied. It was shown that by the grade of influence on the ESR spectrum of complexes the compounds can be divided into three groups. To the 1-st group appertain quinoxaline-2,3-dithiol and SCN~- which change parameters of spin-hamiltonian essentialy and can be detected selectively. To the 2-nd one belongs a list of sulfur containing ligand, for example, Michler thioketone and thiosalicylic acid which lead to disappearance of the spectrum for bonded complexes. To the 3-rd group pertain substances which have no obvious influence on the spectrum's parameters (Br~- OH~-, NO_2~- C_2O~2-).

机译：研究了22种不同性质的有机和无机化合物与共价键合到二氧化硅上的铜（II）-二乙撑三胺配合物的相互作用。结果表明，根据对配合物ESR谱的影响程度，化合物可分为三类。第一组属于喹诺沙林-2,3-二硫醇和SCN〜-，它们改变了自旋哈密顿精要参数，可以被选择性地检测出来。第二类是含硫配体的列表，例如，Michler硫代酮和硫代水杨酸，它们导致键合配合物的光谱消失。第三类是对光谱参数没有明显影响的物质（Br〜-OH〜-，NO_2〜-C_2O〜2-）。

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《Украинский химический журнал》 |1998年第1期|p.12-16|共5页
作者
Zaitsev V.N.; Volkov A.N.; Zub V.Y.;
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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 rus
中图分类化学;
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A study of the interaction of dicthylenetriamine complexes of copper fixed on silica with reagents of different nature by the eSR method

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