Synthesis of cyanide complexes in aprotic solvents

Semenishin D.I.

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Synthesis of cyanide complexes in aprotic solvents

机译：非质子溶剂中氰化物配合物的合成

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The aprotonic solvents (dimethylsulphuric oxide, dimethylformamide, dimethylacetamide) is proposed to use for synthesis of simple and complex d-metals cyanides. The gas-like ammonia cyanide is used as a cyanidation agent. This method allows to obtain cyanides and to eliminate their hydrolysis.

机译：建议将质子惰性溶剂（二甲基亚硫醚，二甲基甲酰胺，二甲基乙酰胺）用于合成简单和复杂的d-金属氰化物。气态氨氰用作氰化剂。该方法允许获得氰化物并消除其水解。

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《Украинский химический журнал》 |1998年第5期|p.8-9|共2页
作者
Semenishin D.I.;
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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种 rus
中图分类化学;
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1. Effect of aprotic solvent medium on the properties of anionic cyanide complexes [J] . Semenishin D.I. Украинский химический журнал . 1998,第6期

机译：非质子溶剂介质对阴离子氰化物配合物性能的影响
2. Addition of metal cyanides to tosylhydrazones of aldehydes in aprotic solvents: A new method for one-carbon homologation of aldehydes and for the synthesis of alpha-(N-2-tosylhydrazino)nitriles [J] . Marczak S., Wicha J. Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2003,第7期

机译：在质子惰性溶剂中将金属氰化物加到醛的甲苯磺酰：中：醛的一碳同系化和合成α-（N-2-甲苯磺酰肼基）腈的新方法
3. Synthesis of Tridentate Schiff base Molybdenum() Complexes and Their Electrochemical Properties in Aprotic Solvents [J] . Chae-Pyeong Rim, Ki-Hyung Chjo, Mi-Sook Song, Journal of the Korean Chemical Society . 1995,第1期

机译：三齿席夫碱钼（）配合物的合成及其在非质子溶剂中的电化学性能
4. SYNTHESIS OF AMINATED PVC'S USING AN APROTIC SOLVENT: DMSO [C] . Robert P. Kusy, John Q. Whitley, Sungyol Lee Society of Plastics Engineers annual technical conference;ANTEC'95 . 1995

机译：使用非质子溶剂DMSO合成改性PVC
5. I. THE SYNTHESIS AND REACTIONS OF CHIRAL 1,3,2-OXAZAPHOSPHOLANE DERIVATIVES. II. KINETIC AND MECHANISTIC STUDIES OF POLYETHER OMEGA-PHASE CATALYZED REACTIONS OF POTASSIUM-CYANIDE WITH BENZYL BROMIDE IN NON-POLAR, APROTIC SOLVENT TOLUENE. [D] . PHAM, VAN TUYET. 1987

机译：I.手性1,3,2-恶唑磷衍生物的合成与反应。二。非极性非质子传递溶剂甲苯中氰化钾与苄基溴的多相催化反应的动力学和机理研究。
6. Solvation properties of natural and synthetic ionophores. I. Stoichiometry of complexes with alkali and alkaline earth cations in aprotic organic solvents. [O] . U Olsher 1982

机译：天然和合成离子载体的溶剂化性质。 I.非质子有机溶剂中碱金属和碱土金属阳离子配合物的化学计量。
7. A Novel Reduction of theO-(3,5-Dinitrobenzoyl)-N,N-(aroylary)hydroxylamines by the Cyanide Ion in Dipolar Aprotic Solvents [O] . Shigeru Oae, Tadamitsu Sakurai 1975

机译：通过氰化离子在偶极非质子溶剂中的氰化物离子进行新的（3,5-二硝基苯甲酰基）-N，N-（芳烃）羟胺的新型氰基胺
8. Reactions of Activated Olefinic and Aromatic Systems with Cyanide Ion and with Certain Carbanions in Aprotic Solvents. [R] . Snyder, H. R. 1973

机译：活性烯烃和芳烃体系与氰化物离子和某些碳负离子在非质子溶剂中的反应。

Synthesis of cyanide complexes in aprotic solvents

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