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Peroxicoagulation and Solar Peroxicoagulation for Landfill Leachate Treatment Using a Cu-Fe System

机译:铜铁系统过氧化物混凝和太阳能过氧化物混凝处理垃圾渗滤液

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摘要

Leachates, particularly those from mature landfills, are difficult to treat by biological processes because of their high toxicity and low biodegradability. Therefore, the development of new treatment technology is necessary. The treatment of landfill leachate by peroxicoagulation and solar peroxicoagulation using a batch electrolytic reactor with a Fe cathode and a Cu anode is proposed. The tested operational variables included pH (2.8 and 8.2), current density (11 and 16mAcm(-2)), treatment time (5, 10, 15, 20, 25, and 30min), and presence of solar ultraviolet (UV) light and were collected using a compound parabolic collector. The optimum conditions were a pH, current density, and treatment time of 2.8, 16mAcm(-2), and 10min, respectively. The presence of UV did not have a significant effect. The chemical oxygen demand and biochemical oxygen demand removed were 62.3% and 55.5%, respectively. The results of UV-visible absorption, fluorescence, and Fourier transform infrared spectroscopy measurements confirm the oxidation process.
机译:渗滤液,特别是来自成熟垃圾填埋场的渗滤液,由于其高毒性和低生物降解性而难以通过生物方法进行处理。因此,有必要开发新的治疗技术。提出了使用具有Fe阴极和Cu阳极的间歇电解反应器通过过氧化物凝结和太阳过氧化物凝结处理垃圾渗滤液的方法。测试的操作变量包括pH值(2.8和8.2),电流密度(11和16mAcm(-2)),处理时间(5、10、15、20、25和30min)以及太阳紫外线(UV)的存在并使用复合抛物线收集器收集。最佳条件是pH值,电流密度和处理时间分别为2.8、16mAcm(-2)和10min。 UV的存在没有显着影响。去除的化学需氧量和生化需氧量分别为62.3%和55.5%。紫外可见吸收,荧光和傅立叶变换红外光谱测量结果证实了氧化过程。

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