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Analysis of Algaecide Exposures: an Evaluation of the I-3(-) Method to Measure Sodium Carbonate Peroxyhydrate Algaecides

机译:除藻剂暴露的分析:I-3(-)方法测量碳酸钠过氧水合除藻剂的评估

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摘要

Algaecides are commonly used to control noxious algal growths in water resources. In order to make accurate predictions about responses of target and non-target species to algaecide exposures, reliable methods are needed to confirm exposures in the laboratory and the field. The focus of this research was to evaluate the I-3(-) method for measuring hydrogen peroxide (H2O2) exposures associated with applications of a sodium carbonate peroxyhydrate (SCP)-based algaecide. To meet this overall objective, method detection limits, interferences from field waters (turbidity, color, and algal cell density), and storage stability of samples were measured. The method detection limits were 0.2 (p< 0.0001) and 0.25 mg H2O2/L (p= 0.0002) for laboratory and field waters, respectively. The upper method detection limit was 7.5 mg H2O2/L for both waters. Turbidity (25.3 NTU) and color of field-collected water did not interfere with measurements. Algal cell densities of 10(4), 10(5), and 10(6) cells/mL of two planktonic algal species in laboratory water did not interfere with measurements. Measurements of samples stored in dark refrigeration and on ice remained stable over 4 days, while measurements of samples stored in direct sunlight in ambient temperatures were altered after 1 day. The I-3(-) method accurately measured H2O2 exposures in the laboratory water, field water, and laboratory water containing planktonic algae used in this experiment within the range of concentrations that would be applied in a field setting. These data demonstrated that this method has utility for confirming exposures after laboratory and field treatments of SCP-based algaecides.
机译:除藻剂通常用于控制有害藻类在水资源中的生长。为了准确预测目标和非目标物种对除藻剂暴露的响应,需要可靠的方法来确认实验室和现场的暴露。这项研究的重点是评估I-3(-)方法来测量与过氧化碳酸钠(SCP)为基础的除藻剂的应用相关的过氧化氢(H2O2)暴露。为了达到这一总体目标,测量了方法的检测限,田间水体的干扰(浊度,颜色和藻类细胞密度)以及样品的存储稳定性。实验室和野外水的方法检出限分别为0.2(p <0.0001)和0.25 mg H2O2 / L(p = 0.0002)。两种水的方法检测上限均为7.5 mg H2O2 / L。浊度(25.3 NTU)和现场收集的水的颜色不会干扰测量。实验室水中的两种浮游藻类的藻类细胞密度为10(4),10(5)和10(6)/ mL不会干扰测量。在黑暗中冷藏和在冰上保存的样品的测量在4天内保持稳定,而在环境温度直射阳光下存储的样品的测量在1天后发生变化。 I-3(-)方法可准确测量实验室用水,野外用水和本实验中所用浮游藻类的实验室水中H2O2的暴露量,该浓度应在野外环境中使用。这些数据表明,该方法可用于实验室和野外处理基于SCP的除藻剂后确认暴露。

著录项

  • 来源
    《Water, Air, and Soil Pollution》 |2015年第6期|170.1-170.9|共9页
  • 作者单位

    Clemson Univ, Dept Forestry, Clemson, SC 29634 USA|Clemson Univ, Dept Environm Conservat, Clemson, SC 29634 USA;

    Clemson Univ, Dept Forestry, Clemson, SC 29634 USA|Clemson Univ, Dept Environm Conservat, Clemson, SC 29634 USA;

    Clemson Univ, Dept Forestry, Clemson, SC 29634 USA|Clemson Univ, Dept Environm Conservat, Clemson, SC 29634 USA;

    Clemson Univ, Dept Forestry, Clemson, SC 29634 USA|Clemson Univ, Dept Environm Conservat, Clemson, SC 29634 USA;

    Clemson Univ, Dept Forestry, Clemson, SC 29634 USA|Clemson Univ, Dept Environm Conservat, Clemson, SC 29634 USA;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Algaecide; Hydrogen peroxide; Sodium carbonate peroxyhydrate;

    机译:除藻剂;过氧化氢;碳酸钠过氧水合物;

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