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Metastable dynamics of the hard-sphere system

机译:硬球系统的亚稳态动力学

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摘要

The reformulation of the mode-coupling theory (MCT) of the liquid-glass transition which incorporates the element of metastability is applied to the hard-sphere system. It is shown that the glass transition in this system is not a sharp one at the special value of the density or the packing fraction, which is in contrast to the prediction by the conventional MCT. Instead we find that the slowing down of the dynamics occurs over a range of values of the packing fraction. Consequently, the exponents governing the sequence of time relaxations in the intermediate time regime are given as functions of the packing fraction, with one additional parameter that describes the overall scale of the metastable potential energy for defects in the hard-sphere system. Implications of the present model on the recent experiments on colloidal systems are also discussed.
机译:包含亚稳性元素的液-玻璃转变的模式耦合理论(MCT)的重新制定应用于硬球系统。结果表明,在该系统中,玻璃化转变在密度或堆积率的特殊值下不是一个尖锐的转变,这与常规MCT的预测相反。相反,我们发现动力学的减慢发生在填充分数的值的范围内。因此,给出了控制中间时间范围内时间弛豫序列的指数,作为填充分数的函数,其中一个附加参数描述了硬球系统中缺陷的亚稳势能的总体规模。还讨论了本模型对胶体系统最新实验的影响。

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