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Studies on xanthate-zinc diethyl dithiocarbamate accelerator combination in natural rubber

机译:天然橡胶中黄药-锌二乙基二硫代氨基甲酸酯促进剂的组合研究

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摘要

Zinc salts of ethyl, isopropyl, and butyl xanthates have been prepared in the laboratory. The synergistic effect of these xanthates with zinc diethyl dithiocarbamate (ZDEC) on the vulcanisation of natural rubber was studied at different temperatures. The amount of the three xanthates and ZDEC in the compounds was optimised by varying the amount of ZDEC from 0 to P25 pphr and the xanthates from 0 to 15 pphr. The cure characteristics were also studied. The rubber gum compounds with the three xanthate accelerators and ZDEC were cured at various temperatures from 60 to 150 deg C. The sheets were moulded and properties such as tensile strength, tear strength, crosslink density, elongation at break, compression set, heat buildup, abrasion resistance, and flex resistance were evaluated. The properties showed that the zinc xanthate-ZDEC accelerator system has a positive synergistic effect on the curing and mechanical properties of natural rubber compounds.
机译:乙基,异丙基和丁基黄药的锌盐已在实验室中制备。研究了在不同温度下这些黄药与二乙基二硫代氨基甲酸锌(ZDEC)对天然橡胶硫化的协同作用。通过将ZDEC的量从0更改为P25 pphr,将黄药的含量从0更改为15 pphr,可以优化化合物中三种黄药的含量和ZDEC的含量。还研究了固化特性。将具有三种黄原酸酯促进剂和ZDEC的橡胶胶料在60至150摄氏度的各种温度下固化。对片材进行模塑,并测定其性能,例如拉伸强度,撕裂强度,交联密度,断裂伸长率,压缩形变,发热,评价耐磨性和挠曲性。性能表明,黄药酸锌-ZDEC促进剂体系对天然橡胶胶料的硫化和机械性能具有积极的协同作用。

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