The first catalytic enantioselective Nozaki-Hiyama-Kishi reaction

Bandini M.; Umani-Ronchi A.; Cozzi PG.

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The first catalytic enantioselective Nozaki-Hiyama-Kishi reaction

机译：第一个催化对映选择性的野崎崎山喜树反应

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Herein we report the first example of a catalytic enantioselective Nozaki-Hiyama-Kishi reaction performed with a catalytic amount of chiral chromium complex. A large variety of non-stereogenic and stereogenic reactive halides can be added to aldehydes to afford the corresponding alcohols with excellent stereoselectivity using a catalytic amount of chiral chromium complex (C) 2000 Elsevier Science Ltd All rights reserved. [References: 10]

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《Polyhedron: The International Journal for Inorganic and Organometallic Chemistry》 |2000年第5期|共3页
作者
Bandini M.; Umani-Ronchi A.; Cozzi PG.;
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正文语种 eng
中图分类化学;无机化学;
关键词
Chromium; Salen; Manganese; Catalysis; Enantioselection; Nozaki-hiyama-kishi reaction; Bond formations; Complexes;

机译：铬;Salen;锰;催化;对映异构;野崎一希希反应;键的形成;络合物;

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1. The synthesis of a new class of chiral pincer ligands and their applications in enantioselective catalytic fluorinations and the Nozaki-Hiyama-Kishi reaction [J] . Deng Q.-H., Wadepohl H., Gade L.H. Chemistry: A European journal . 2011,第52期

机译：新型手性钳位配体的合成及其在对映选择性催化氟化和野崎-山山-纪志反应中的应用
2. A Chiral Bipyridyl Alcohol for Catalytic Enantioselective Nozaki-Hiyama-Kishi Allylation of Aldehydes and Ketones [J] . Chen Rui-Yu, Dhondge Attrimuni P., Lee Gene-Hsian, Advanced synthesis & catalysis . 2015,第5期

机译：手性联吡啶醇用于醛和酮的催化对映选择性野崎-喜山-喜士烯丙基化
3. Synthesis of non-symmetric bis(oxazoline)-containing ligands and their application in the catalytic enantioselective Nozaki-Hiyama-Kishi allylation of benzaldehyde [J] . Organic & biomolecular chemistry . 2008,第3期

机译：含不对称双（恶唑啉）的配体的合成及其在苯甲醛催化对映选择性Nozaki-Hiyama-Kishi烯丙基化中的应用
4. Microwave Specific Effect on Catalytic Enantioselective Reactions [C] . Tohru Yamada Asia-Pacific Microwave Conference . 2018

机译：微波对催化对映选择性反应的影响
5. I. Enantioselective total synthesis of quinine and quinidine. II. Thiourea-catalyzed enantioselective C-C bond-forming reactions. a. Catalytic asymmetric N-acyliminium ion cyclizations. b. Catalytic asymmetric aza-Baylis-Hillman reactions [D] . Raheem, Izzat Tiedje 2008

机译：I.奎宁和奎尼丁的对映选择性全合成。二。硫脲催化的对映选择性C-C键形成反应。一个。催化不对称N-酰亚胺离子环化。 b。催化不对称氮杂-Baylis-Hillman反应
6. Catalytic Enantioselective Stereoablative Reactions: An Unexploited Approach to Enantioselective Catalysis [O] . Justin T. Mohr, David C. Ebner, Brian M. Stoltz -1

机译：催化对映选择性立体消解反应：对映选择性催化的一种未开发的方法。
7. The stereochemistry of the Nozaki-Hiyama-Kishi reaction and the construction of 10-membered lactones. the enantioselective total synthesis of (-)-decarestrictine D. [O] . Pilli, RA, Victor, MM 2015

机译：Nozaki-Hiyama-Kishi反应的立体化学和10元内酯的构建。（-）-去卡地丁D的对映选择性全合成。

The first catalytic enantioselective Nozaki-Hiyama-Kishi reaction

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