A Fluorous,Pummerer Cyclative-Capture Strategy for the Synthesis of N-Heterocycles

Laura A.McAHister; Rosemary A.McCormick; Karen M.James

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A Fluorous,Pummerer Cyclative-Capture Strategy for the Synthesis of N-Heterocycles

机译：氟，Pummerer循环捕获策略，用于合成N-杂环

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A fluorous,cyclative-capture strategy based on a new Pummerer cycliza-tion process allows rapid access to tagged,heterocyclic frameworks.Convenient modification of the fluorous,heterocyclic scaffolds by using a variety of approaches including Pd-catalyzed cross-couplings is possible.Traceless,reductive cleavage of the fluorous-phase tag or oxidative cleavage and further elaboration,completes a strategy for the high-throughput,fluorous-phase synthesis of a diverse range of N-heterocycles.

机译：基于新的Pummerer环化工艺的氟环化捕获策略可以快速访问标记的杂环骨架。通过使用多种方法（包括Pd催化的交叉偶联）方便地修饰氟，杂环骨架。氟相标签的还原裂解或氧化裂解，以及进一步的完善，完成了高通量，氟相合成各种N-杂环的策略。

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《Chemistry: A European journal》 |2007年第4期|共14页
作者
Laura A.McAHister; Rosemary A.McCormick; Karen M.James;
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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
fluorous-phase synthesis; heterocycles; organic synthesis; pummerer reaction; samarium;

机译：氟相合成;杂环;有机合成;聚甲醛反应;sa;

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专利

1. A fluorous, pummerer cyclative-capture strategy for the synthesis of N-heterocycles [J] . McAllister LA, McCormick RA, James KM, Chemistry: A European journal . 2007,第26期

机译：一种用于合成N-杂环的氟，pummerer循环捕获策略
2. Developing New Cleavage Strategies in a Fluorous Phase Pummerer Cyclative-Capture Approach for the Synthesis of N-Heterocycles [J] . Rosemary A. McCormick, Karen M. James, Nigel Willetts, QSAR & combinatorial science . 2006,第8a9期

机译：在氟相Pummerer循环捕获方法中开发新的裂解策略以合成N-杂环。
3. A Fluorous-Phase Pummerer Cyclative-Capture Strategy for the Synthesis of Nitrogen Heterocycles [J] . Laura A. McAllister, Rosemary A. McCormick, Stephen Brand, Angewandte Chemie . 2005,第3期

机译：氮杂杂环的氟相Pummerer循环捕获策略
4. SYNTHESIS OF TWO C-14 LABELED CYCLOOXYGENASE-II INHIBITORS VIA A PUMMERER DEGRADATION-RESYNTHESIS STRATEGY [C] . Charles S. Elmore, Dennis C. Dean, Tina M. Marks, International Symposium on the Synthesis and Applications of Isotopes and Isotopically Labelled Compounds . 2004

机译：通过Pammerer降解 - 重新合成策略合成两种C-14标记的环氧基酶-II抑制剂
5. New immobilization and recovery strategies: Design and synthesis of compounds, reagents, and catalysts with high fluorous phase affinities. [D] . Rocaboy, Christian. 2002

机译：新的固定化和回收策略：设计和合成具有高氟相亲合力的化合物，试剂和催化剂。
6. A minimal fluorous tagging strategy enables the synthesis of the complete stereoisomer library of Sch725674 macrolactones [O] . Jared D. Moretti, Xiao Wang, Dennis P. Curran -1

机译：一个最小的氟标记策略使sch725674大环内酯的完整立体库的合成
7. Fluorous Synthesis: A Fluorous-Phase Strategy for Improving Separation Efficiency in Organic Synthesis [O] . Armido Studer, Sabine Hadida, Rafael Ferritto, 2014

机译：氟合成：一种提高有机合成分离效率的荧光相策略

A Fluorous,Pummerer Cyclative-Capture Strategy for the Synthesis of N-Heterocycles

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