Design of phase-vanishing reactions

Van Zee N.J.; Dragojlovic V.

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Design of phase-vanishing reactions

机译：相消失反应的设计

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Phase-vanishing reactions utilize a perfluorinated solvent as a liquid membrane to separate a substrate and a reagent. Since their introduction less than ten years ago, phase-vanishing reactions have become a valuable alternative to reactions that require a slow addition of a reagent. A variety of experimental designs allow reactions to be carried out under anhydrous conditions, under photolytic conditions, under solvent-free conditions, with a gas as a reagent, and under reflux.

机译：相消失反应利用全氟化溶剂作为液膜分离底物和试剂。自从不到十年前问世以来，相消失反应已成为需要缓慢添加试剂的反应的宝贵替代品。多种实验设计允许反应在无水条件下，在光解条件下，在无溶剂条件下，以气体为试剂并在回流下进行。

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《Chemistry: A European journal》 |2010年第27期|共9页
作者
Van Zee N.J.; Dragojlovic V.;
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原文格式 PDF
正文语种 eng
中图分类应用化学;
关键词
Experimental designs; Liquid membranes; Perfluorinated solvents; Phase screens; Synthesis design;

机译：实验设计;液膜;全氟化溶剂;相筛;合成设计;

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1. The role of neat substrates in phase-vanishing and tandem phase-vanishing reactions [J] . Nicole Windmon, Veljko Dragojlovic Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2008,第46期

机译：纯净底物在相消失和串联相消失反应中的作用
2. Design of Phase-Vanishing Reactions [J] . Nathan J. Van Zee, Veljko Dragojlovic Prof. Dr. Chemistry - A European Journal . 2010,第27期

机译：相消失反应的设计
3. Application of phase-vanishing method with CO gas evolution to carbonylation reactions [J] . Yusuke Adachi, Hiroshi Matsubara Journal of Fluorine Chemistry . 2018,第期

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4. Kinetics of the Reactions of H and CH_3 Radicals with nButane: An Experimental Design Study using Reaction Network Analysis [C] . David A. Sheen, Jeffrey A. Manion US National Combustion Meeting . 2013

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5. Design and synthesis of novel chiral arsines for asymmetric Wittig reactions and palladium-catalyzed asymmetric allylic alkylation and asymmetric Heck reactions. [D] . Wu, Huafeng. 2004

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6. Solvent-free phase-vanishing reactions with PTFE (Teflon®) as a phase screen [O] . Kevin Pels, Veljko Dragojlovic 2009

机译：PTFE（Teflon®）作为相筛的无溶剂消相反应
7. Design of Phase-Vanishing Reactions [O] . Nathan J. Van Zee, Veljko Dragojlovic 2010

机译：设计消失反应的设计

Design of phase-vanishing reactions

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