Gold catalysis: No steric limitations in the phenol synthesis

Hashmi ASK; Salathe R; Frey W

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Gold catalysis: No steric limitations in the phenol synthesis

机译：金催化：苯酚合成中没有空间限制

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Different dihydroisoindol-4-ols and 8-hydroxytetrahydroisoquinolines were prepared by the gold-catalyzed phenol synthesis. The reaction was investigated with several sterically demanding groups in the 5-position of the furan starting material. The influence of the reaction time and the catalyst on the yield was investigated.

机译：通过金催化的苯酚合成制备了不同的二氢异吲哚-4-醇和8-羟基四氢异喹啉。用呋喃原料的5-位上的几个空间要求基团研究了该反应。研究了反应时间和催化剂对产率的影响。

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《Chemistry: A European journal》 |2006年第26期|共6页
作者
Hashmi ASK; Salathe R; Frey W;
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正文语种 eng
中图分类化学;
关键词
cyclization; dihydroisoindoles; gold; homogeneous catalysis; tetrahydroisoquinolines; FURANS; DERIVATIVES; CONVERSION; COMPLEXES; SECONDARY; KETONES; ALKYNES; ARENES;

机译：环化;二氢异吲哚;金;均相催化;四氢异喹啉;呋喃;衍生物;转化;络合物;仲;酮;炔烃;芳烃;

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1. Gold catalysis: No steric limitations in the phenol synthesis [J] . Hashmi ASK, Salathe R, Frey W Chemistry: A European journal . 2006,第26期

机译：金催化：苯酚合成中没有空间限制
2. Traversing Steric Limitations by Cooperative Lewis Base/Palladium Catalysis: An Enantioselective Synthesis of alpha-Branched Esters Using 2-Substituted Allyl Electrophiles [J] . Schwarz Kevin J., Pearson Colin M., Cintron-Rosado Gabriel A., Angewandte Chemie . 2018,第26期

机译：通过合作Lewis基碱/钯催化来横穿空间限制：使用2-取代的烯丙基电子药物对α-支链酯的对映选择性合成
3. Gold catalysis contra platinum catalysis in hydroarylation contra phenol synthesis [J] . A. Stephen K. Hashmi, Elzen Kurpejovic, Wolfgang Frey, Tetrahedron . 2007,第26期

机译：金催化对铂催化加氢芳烃对苯酚合成。
4. SELECTIVE CATALYSIS AND ACTIVE STRUCTURES FOR DIRECT PHENOL SYNTHESIS AND CH4 REFORMING [C] . Mizuki Tada, Linsheng Wang, Shin-ichi Nagamatsu National Meeting Exhibition . 2013

机译：直接酚合成和CH4重整的选择性催化和活性结构
5. Copper Catalysis in Organic Synthesis of Alkyl Fluorides, Sterically Hindered Anilines, and 1,4-Dienes [D] . Mailig, Melrose T. 2017

机译：有机合成烷基氟化物，位阻苯胺和1,4-二烯时的铜催化作用
6. Traversing Steric Limitations via Cooperative Lewis Base/Pd Catalysis: An Enantioselective Synthesis of α-Branched Esters using 2-Substituted Electrophiles [O] . Kevin J. Schwarz, Dr. Colin M. Pearson, Gabriel A. Cintron-Rosado, -1

机译：通过协作的Lewis碱/ Pd催化穿越立体限制：使用2取代的亲电试剂的α-支链酯的对映选择性合成
7. Traversing Steric Limitations by Cooperative Lewis Base/Palladium Catalysis: An Enantioselective Synthesis of α‐Branched Esters Using 2‐Substituted Allyl Electrophiles [O] . Kevin J. Schwarz, Colin M. Pearson, Gabriel A. Cintron‐Rosado, 2018

机译：通过合作Lewis基碱/钯催化来横穿空间限制：使用2取代的烯丙基电子药物对α-支链酯的对映选择性合成

Gold catalysis: No steric limitations in the phenol synthesis

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