Hexagonal supramolecular architectures from ferrocenium cations incorporating [Ni(mnt)(2)](-) columns: Structures and properties of [alkylferrocene][Ni(mnt)(2)](-) charge-transfer complexes (mnt = maleonitriledithiolate)

Mochida T; Koinuma T; Akasaka T; Sato M; Nishio Y; Kajita K; Mori H

首页> 外文期刊>Chemistry: A European journal >Hexagonal supramolecular architectures from ferrocenium cations incorporating [Ni(mnt)(2)](-) columns: Structures and properties of [alkylferrocene][Ni(mnt)(2)](-) charge-transfer complexes (mnt = maleonitriledithiolate)

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Hexagonal supramolecular architectures from ferrocenium cations incorporating [Ni(mnt)(2)](-) columns: Structures and properties of [alkylferrocene][Ni(mnt)(2)](-) charge-transfer complexes (mnt = maleonitriledithiolate)

机译：含[Ni（mnt）（2）]（-）柱的二茂铁阳离子的六边形超分子结构：[烷基二茂铁] [Ni（mnt）（2）]（-）电荷转移配合物的结构和性质（mnt =马来腈三硫代磺酸盐）

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The crystal architecture, magnetic properties, and thermodynamic properties of [n-butylferrocene] [Ni(mnt)(2)] (1), [tert-butylferrocene][Ni(mnt)(2)] (2), [1,1'-diethylferrocene][Ni(mnt)(2)] (3), and [1,1'-diisopropylferrocene][Ni(mnt),] (4) were investigated (mnt = maleonitriledithiolate). These complexes exhibit a unique supra-molecular structure in which the ferrocenium cations constitute honeycomb-like assembled structures surrounding columns of the anions. For 1, the cations form a dimer through a very short intermolecular ferrocene-ferrocene distance of 3.28 angstrom, which mediates an antiferromagnetic interaction with a singlet-triplet energy gap of 5 K. First-order phase transitions occur in 1-3 at 364, 361, and 350 K, respectively, accompanied by thermal hysteresis.

机译：[正丁基二茂铁] [Ni（mnt）（2）]（1），[叔丁基二茂铁] [Ni（mnt）（2）]（2），[1]的晶体结构，磁性和热力学性质研究了1'-二乙基二茂铁] [Ni（mnt）（2）]（3）和[1,1'-二异丙基二茂铁] [Ni（mnt），]（4）（mnt =顺丁烯二腈）。这些配合物表现出独特的超分子结构，其中二茂铁阳离子构成围绕阴离子柱的蜂窝状组装结构。对于1，阳离子通过非常短的分子间二茂铁-二茂铁间距3.28埃形成二聚体，介导反铁磁相互作用且单重态-三重态能隙为5K。一阶相变发生在1-3的364， 361和350 K分别伴有热滞。

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《Chemistry: A European journal》 |2007年第6期|共10页
作者
Mochida T; Koinuma T; Akasaka T; Sato M; Nishio Y; Kajita K; Mori H;
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正文语种 eng
中图分类化学;
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crystal engineering; magnetic properties; metallocenes; pi interactions; self-assembly; TRANSFER SALTS; MAGNETIC-PROPERTIES; COORDINATION POLYMERS; PHYSICAL-PROPERTIES; CRYSTAL-STRUCTURE; DECAMETHYLFERROCENIUM SALTS; INTERMOLECULAR INTERACTIONS; MOLECULAR CONDUCTORS; VALENCE STATES; NI;

机译：晶体工程;磁性;茂金属;π相互作用;自组装;转移盐;磁性体;配位聚合物;物理性质;晶体结构;十烷基FER铁盐;分子间相互作用;分子导体;价态;

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1. Hexagonal supramolecular architectures from ferrocenium cations incorporating [Ni(mnt)(2)](-) columns: Structures and properties of [alkylferrocene][Ni(mnt)(2)](-) charge-transfer complexes (mnt = maleonitriledithiolate) [J] . Mochida T, Koinuma T, Akasaka T, Chemistry: A European journal . 2007,第6期

机译：含[Ni（mnt）（2）]（-）柱的二茂铁阳离子的六边形超分子结构：[烷基二茂铁] [Ni（mnt）（2）]（-）电荷转移配合物的结构和性质（mnt =马来腈三硫代磺酸盐）
2. Design and properties of mixed metal multinuclear molecules Part 1. Molecular structures of [Ag(PR3)(2)](2)[Ni(mnt)(2)] type complexes (R = Me, Et, Cy and mnt = maleonitriledithiolate) and [AgL](2)[Ni(mnt)(2)] type complexes with chelating diphosphin [J] . Youm KT., Do Y., Jun MJ., Inorganica Chimica Acta . 2000,第2期

机译：混合金属多核分子的设计和性质第1部分。[Ag（PR3）（2）]（2）[Ni（mnt）（2）]型配合物的分子结构（R = Me，Et，Cy和mnt =顺丁烯二腈）和[AgL]（2）[Ni（mnt）（2）]型配合物与螯合二膦
3. Biferrocene-M(mnt)_2 Charge-Transfer Complexes (M=Ni,Co;mnt=Maleonitriledithiolate).Structure,Valence States,and Magnetic Properties [J] . Tomoyuki Mochida, Kousuke Takazawa, Hideaki Matsui, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第23期

机译：双茂铁-M（mnt）_2电荷转移配合物（M = Ni，Co; mnt =马来三硫代马来酸）。结构，价态和磁性
4. Ni-S(uper)O(xide)D(ismutase) Inspired Ni(Ⅱ)-Amino Acid Complexes Covalently Grafted onto Merrifield's Resin - Synthesis, Structure and Catalytic Activity [C] . Z. Csendes, J.T. Kiss, B. Kutus, International materials symposium . 2013

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5. Syntheses, characterization and catalytic properties of Zn(II) and Ni(II) complexes: Modeling the active sites of zinc and nickel enzymes. [D] . Khan, Ahmad Raza. 1999

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6. Electron Spin Resonance Studies of the Reorientational Motion of Ni(mnt)2− [O] . Bruce A. Kowert, Eva M. Thurman-Keup, Ann Joern Stemmler, -1

机译：电子自旋Ni的重取向运动（mNT）的共振研究2-
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机译：紫精M（mnt）2电荷转移盐的组装结构和磁性质（mnt =顺丁烯二腈； M = Cu，Ni，Pt）

Hexagonal supramolecular architectures from ferrocenium cations incorporating [Ni(mnt)(2)](-) columns: Structures and properties of [alkylferrocene][Ni(mnt)(2)](-) charge-transfer complexes (mnt = maleonitriledithiolate)

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