Intramolecular Hydrogen Bonding in Calixarenes

Rudkevich Dmistry M.

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Intramolecular Hydrogen Bonding in Calixarenes

机译：杯芳烃中的分子内氢键

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摘要

The construction of a molecular cavity for recognition and catalysis requires either covalent synthesis or intermolecular self-assembly of complementary units. Intramolecular hydrogen bonding is another tool to control the cavity-forming process. When properly positioned within the same molecular structure, hydrogen bonding sites are responsible for the formation, preorganization, and binding ability of the host. The most typical examples from the supramolecular chemistry of calixarenes, the key cavity-containing building blocks, and derived form them reacepotr molecules are discussed.

机译：用于识别和催化的分子腔的构建需要共价合成或互补单元的分子间自组装。分子内氢键是控制空穴形成过程的另一种工具。当正确定位在同一分子结构内时，氢键合位点负责宿主的形成，预组织和结合能力。讨论了杯芳烃的超分子化学中最典型的例子，关键的含腔结构单元以及由它们衍生的acepotpot分子。

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《Chemistry: A European journal》 |2000年第15期|共8页
作者
Rudkevich Dmistry M.;
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正文语种 eng
中图分类化学;应用化学;
关键词
calixarenes; hydrogen bonds; molecular recognition; supramolecular chemistry;

机译：杯芳烃;氢键;分子识别;超分子化学;

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Intramolecular Hydrogen Bonding in Calixarenes

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