Catalytic Ionic Hydrogenations

R.Morris Bullock

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Catalytic Ionic Hydrogenations

机译：催化离子加氢

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Catalytic ionic hydrogenation of ketones occurs by proton transfer to a ketone from a cationic metal dihydride,followed by hydride transfer from a neutral metal hydride.This contrasts with traditional catalysts for ketone hydrogenation that require binding of the ketone to the metal and subsequent insertion of the ketone into a M-H bond.Ionic hydrogenation catalysts based on the inexpensive metals molybdenum and tungsten have been developed based on mechanistic understanding of the individual steps required in the catalytic reaction.

机译：酮的催化离子加氢是通过将质子从阳离子金属二氢化物转移至酮而发生的，随后是从中性金属氢化物转移氢，这与传统的酮加氢催化剂相反，后者需要将酮与金属结合并随后插入基于对催化反应所需各个步骤的机械理解，已开发出了基于廉价金属钼和钨的离子加氢催化剂。

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《Chemistry: A European journal》 |2004年第10期|共9页
作者
R.Morris Bullock;
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正文语种 eng
中图分类化学;
关键词
homogeneous catalysis; hydride ligands; hydride transfer; hydrogenation; protonation;

机译：均相催化;氢化物配体;氢化物转移;加氢;质子化;

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1. Ionic liquid based Ru(II)-phosphinite compounds and their catalytic use in transfer hydrogenation: X-ray structure of an ionic compound 1-chloro-3-(3-methylimidazolidin-1-yl)propan-2-ol [J] . Murat Aydemir, Khadichakhan Rafikova, Nurzhamal Kystaubayeva, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2014,第Null期

机译：离子液体基Ru（II）-亚膦酸酯化合物及其在转移加氢中的催化用途：离子化合物1-氯-3-（3-甲基咪唑啉-1-基）丙-2-醇的X射线结构
2. Influence of Ionic Association, Transport Properties, and Solvation on the Catalytic Hydrogenation of 1,3-Cyclohexadiene in Ionic Liquids [J] . Ajda Podgorsek, Gorka Salas, Paul S. Campbell The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2011,第42期

机译：离子缔合，输运性质和溶剂化对离子液体中1,3-环己二烯催化加氢的影响
3. Catalytic hydrogenation of levulinic acid in ionic liquid mixtures using hydrogen gas in high-pressure CO2 [J] . Guo Haixin, Tomoka Shida, Smith Richard Lee Jr. The Journal of Supercritical Fluids . 2020,第1期

机译：高压二氧化碳中氢气催化氢化离子液体混合物中的乙酰酸
4. Fabrication of Platinum Nanoparticles through Ionic Liquid Method and Its Catalytic Properties in Hydrogenation Reaction [C] . Liuliu Ding, Guojian Jiang, Wenjun Li, Chinese materials congress . 2013

机译：离子液体法制备铂纳米粒子及其在加氢反应中的催化性能
5. Stoichiometric, catalytic and enantioface-selective hydrogenation of carbon-nitrogen double bonds by an ionic mechanism. [D] . Magee, Matthew Patrick. 2001

机译：通过离子机理对碳氮双键进行化学计量，催化和对映体选择性氢化。
6. Alkaline ionic liquids applied in supported ionic liquid catalyst for selective hydrogenation of citral to citronellal [O] . Eero Salminen, Pasi Virtanen, Jyri-Pekka Mikkola 2014

机译：碱性离子液体在负载型离子液体催化剂中的应用用于将柠檬醛选择性氢化为香茅醛
7. Ionic Ru complex with recyclability by electro-adsorption for efficient catalytic transfer hydrogenation of aryl ketones [O] . Chuan-Jun Yue, Qiu-Neng Xu, Li-Ping Gu, 2017

机译：具有通过电吸收的离子Ru复合物，用于高效催化转移芳基酮的催化转移氢化

Catalytic Ionic Hydrogenations

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