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首页> 外文期刊>The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical >Electrical Interaction of a System Containing Arbitrary Shaped, Ion-Penetrable Charged Particles
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Electrical Interaction of a System Containing Arbitrary Shaped, Ion-Penetrable Charged Particles

机译：包含任意形状的可离子渗透的带电粒子的系统的电相互作用

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摘要

A mean field approach is proposed to derive the electrical interaction energy for a system containing ark shaped, ion-penetrable particles bearing fixed charges in an electrolyte solution. We show that this can be decomposed into the product of two terms. One of these terms is a function of particle properties, and the other term is independent of particle properties. The electrical interaction energies of spheroids are evaluated. Numerical results are presented to show that arbitrary assumptions concerning the shape of a particle can lead to a significant deviation in the estimation of the electrical interaction energy. Care be taken in estimating the properties of a particle on the basis of the electrical interaction energy.
机译：提出了一种平均场方法来为包含电解质溶液中带有固定电荷的方舟形，可离子渗透的颗粒的系统推导电相互作用能。我们证明这可以分解为两个项的乘积。这些术语中的一个是颗粒性质的函数，另一个术语与颗粒性质无关。评估了球体的电相互作用能。数值结果表明，关于颗粒形状的任意假设会导致电相互作用能的估计发生重大偏差。在根据电相互作用能估算颗粒的性质时要格外小心。

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