EPR AND MN-55 CW-ENDOR STUDY OF AN ANTIFERROGMAGNETICALLY COUPLED DINUCLEAR MANGANESE ((MNMNIV)-MN-III) COMPLEX

Zweygart W.; Wieghardt K.; Lubitz W.; Bittl R.

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EPR AND MN-55 CW-ENDOR STUDY OF AN ANTIFERROGMAGNETICALLY COUPLED DINUCLEAR MANGANESE ((MNMNIV)-MN-III) COMPLEX

机译：抗铁磁耦合核锰（（MNMNIV）-MN-III）配合物的EPR和MN-55 CW末端研究

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X- and Q-band EPR and Mn-55 cw-ENDOR experiments are reported on a binuclear ore-bridged dimanganese (MnMnIV)-Mn-III complex. Consistent simulations of spectra from both frequency bands using one parameter set for the orthorhombic g tensor and Mn-III and Mn-IV hyperfine tensors are achieved. Information on the manganese hyperfine couplings is independently obtained from Mn-55 cw-ENDOR spectroscopy performed on both ions. [References: 25]

机译：X波段和Q波段的EPR和Mn-55 cw-ENDOR实验是在双核矿石桥联的二锰（MnMnIV）-Mn-III络合物上报道的。使用正交正交张量和Mn-III和Mn-IV超精细张量的一个参数集实现了来自两个频带的频谱的一致仿真。有关锰超精细偶联的信息可从对两种离子进行的Mn-55 cw-ENDOR光谱中独立获得。 [参考：25]

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《Chemical Physics Letters》 |1996年第3期|共5页
作者
Zweygart W.; Wieghardt K.; Lubitz W.; Bittl R.;
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正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Mixed-valence interactions; Oxygen-evolving complex; Thermus-thermophilus; Electronic-structure; Magnetic-properties; Water oxidation; Metal-complexes; Catalase; Resonance; Simulation;

机译：混合价相互作用;放氧复合物;嗜热嗜热菌;电子结构;磁性;水氧化;金属配合物;过氧化氢酶;共振;模拟;

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1. EPR AND MN-55 CW-ENDOR STUDY OF AN ANTIFERROGMAGNETICALLY COUPLED DINUCLEAR MANGANESE ((MNMNIV)-MN-III) COMPLEX [J] . Zweygart W., Wieghardt K., Lubitz W., Chemical Physics Letters . 1996,第3期

机译：抗铁磁耦合核锰（（MNMNIV）-MN-III）配合物的EPR和MN-55 CW末端研究
2. A combined high-field EPR and quantum chemical study on a weakly ferromagnetically coupled dinuclear Mn(III) complex. A complete analysis of the EPR spectrum beyond the strong coupling limit [J] . Marius Retegan, Marie-Noelle Collomb, Frank Neese Physical chemistry chemical physics: PCCP . 2013,第1期

机译：弱铁磁耦合双核Mn（III）配合物的高场EPR和量子化学研究相结合。超出强耦合极限的EPR频谱的完整分析
3. A combined high-field EPR and quantum chemical study on a weakly ferromagnetically coupled dinuclear Mn(III) complex. A complete analysis of the EPR spectrum beyond the strong coupling limit [J] . Marius Retegan, Marie-Noelle Collomb, Frank Neese Physical chemistry chemical physics: PCCP . 2013,第1期

机译：弱铁磁耦合双核Mn（III）配合物的高场EPR和量子化学研究相结合。超出强耦合极限的EPR频谱的完整分析
4. EPR Studies and Ferromagnetic Interaction of a Dinuclear Copper Complex Mediated by mu-1,1 Bridging Azido Group of the Ligand Hsalamp [C] . R. Srinivasan, B. Natarajan, R. Venkatesan Asia-Pacific EPR/ESR Symposium . 2006

机译：通过MU-1,1桥接氮杂铜铜介导的二核铜复合物的EPR研究和铁磁性相互作用的配体Hsalamp
5. The synthesis and characterization of mononuclear manganese(II), dinuclear manganese(III) and copper(II) complexes. [D] . Yisgedu, Teshome Beyene. 2001

机译：单核锰（II），双核锰（III）和铜（II）配合物的合成与表征。
6. Multifrequency Pulsed EPR Studies of Biologically Relevant Manganese(II) Complexes [O] . T. A. Stich, S. Lahiri, G. Yeagle, -1

机译：生物相关锰（II）配合物的多频脉冲EPR研究
7. Metal Complexes of Benzene Derivatives .45. Dinuclear Bis(Eta(6)-Arene)Vanadium and -chromium complexes containing 1,3-Disilacyclobutane as a Spacer - an Epr Study of Intermetallic Communication [O] . Elschenbroich C., Bretschneider-Hurley A., Hurley J., 1995

机译：苯衍生物的金属配合物.45。 1,3-二硅环丁烷作为间隔物的双核双（Eta（6）-芳烃）钒和铬配合物-金属间通信的EPr研究

EPR AND MN-55 CW-ENDOR STUDY OF AN ANTIFERROGMAGNETICALLY COUPLED DINUCLEAR MANGANESE ((MNMNIV)-MN-III) COMPLEX

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