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Preparation of nanocrystalline TiO_2 (anatase) films

机译:纳米TiO_2(锐钛矿)薄膜的制备

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摘要

Titanium dioxide is undoubtedly one of the widely used and low-cost materials. Usually the TiO_2 material of which the grain size is above the micrometer scale and contains many impurities can only serve as a white pigment in paint, paper, grinding compound, toothpaste, cosmetic products, etc. Because of its semiconductivity property, TiO_2 has wide application, such as oxygen sensor, humid sensor, etc. TiO_2 is also used as good catalyst which can destroy a variety of organic dyes by means of photocatalysis decomposition, providing an efficient method for solving the problem of pollution of the organic dyes. After the pioneering work of Fujishima and Honda's in 1972, there has been increasing interest in employing this material in photoelectrochemical cell. With the rapid development in research of nano-materials recently, it was discovered that nano-TiO_2 plays a more and more important role in photocatalysis decomposition. Especially, the group led by Gratzel made an important breakthrough in photoelectrochemical solar cell by using nanocrystalline TiO_2 porous films, and they have also achieved a good result in rechargeable lithium batteries (such as Li/LCF_3SO_3+PC/TiO_2) by using nanocrystalline TiO_2 films as an electrode.
机译:二氧化钛无疑是被广泛使用且低成本的材料之一。通常,粒径大于微米级且含有很多杂质的TiO_2材料只能用作油漆,纸张,研磨化合物,牙膏,化妆品等中的白色颜料。由于TiO_2具有半导电性,因此具有广泛的应用TiO_2还被用作优良的催化剂,可以通过光催化分解破坏多种有机染料,为解决有机染料的污染问题提供了一种有效的方法。在1972年Fujishima和Honda的开创性工作之后,人们越来越有兴趣在光电化学电池中使用这种材料。随着近来纳米材料研究的飞速发展,人们发现纳米TiO_2在光催化分解中起着越来越重要的作用。特别是,由Gratzel领导的小组通过使用纳米TiO_2多孔膜在光电化学太阳能电池方面取得了重要突破,并且通过使用纳米TiO_2膜在可充电锂电池(如Li / LCF_3SO_3 + PC / TiO_2)中也取得了良好的成绩。作为电极。

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