...
首页> 外文期刊>Zeitschrift fur Anorganische und Allgemeine Chemie >Synthesis and characterization of a novel energetic complex [Cd(DAT) _6](NO_3)_2 (DAT = 1,5-diamino-tetrazole) with high nitrogen content
【24h】

Synthesis and characterization of a novel energetic complex [Cd(DAT) _6](NO_3)_2 (DAT = 1,5-diamino-tetrazole) with high nitrogen content

机译:高氮含量新型高能配合物[Cd(DAT)_6](NO_3)_2(DAT = 1,5-二氨基四唑)的合成与表征

获取原文
获取原文并翻译 | 示例
           

摘要

The novel high nitrogen-containing energetic complex [Cd(DAT) _6](NO_3)_2was synthesized by reaction of Cd(NO_3)_2·6H_2O with 1,5-diamino-tetrazole (DAT). It was characterized by elemental analysis, FT-IR spectroscopy and single-crystal X-ray diffraction, analysis. The central Cd~(2+) ion is coordinated by six nitrogen atoms from six DAT ligand molecules to form a hexacoordinate distorted octahedral compound. The [Cd(DAT)_6](NO _3)_2 molecules are linked together through two types of hydrogen bonds thus forming a stable three-dimensional net structure. The thermal decomposition mechanism of [Cd(DAT)_6](NO_3) _2 was investigated by DSC and TG/DTG analyses and FT-IR spectroscopy. The kinetic parameters of the exothermic process were studied by using Kissinger's and Ozawa-Doyle's methods.
机译:通过Cd(NO_3)_2·6H_2O与1,5-二氨基四唑(DAT)反应合成了新型的高含氮高能配合物[Cd(DAT)_6](NO_3)_2。通过元素分析,FT-IR光谱和单晶X射线衍射,分析对其进行表征。中心的Cd〜(2+)离子由六个DAT配体分子中的六个氮原子配位,形成六配位扭曲的八面体化合物。 [Cd(DAT)_6](NO_3)_2分子通过两种氢键连接在一起,从而形成稳定的三维网状结构。通过DSC和TG / DTG分析以及FT-IR光谱研究了[Cd(DAT)_6](NO_3)_2的热分解机理。放热过程的动力学参数是使用基辛格(Kissinger)方法和小泽(Ozawa-Doyle)方法研究的。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号