The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment

Khrustalev VN; Chernov OV; Aysin RR; Portnyagin IA; Nechaev MS; Bukalov SS

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The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment

机译：较重的14族元素与过渡金属之间的异核键合：一种新型的三氧锡酸铁复合物，具有不寻常的锡酸根碎片

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A new trioxystannate-transition metal complex, {[Li][(Me-2-NCH2CH2O)(3)Sn-Fe(CO)(4)]}(2) (3), exhibiting an unusual type of the heteronuclear bonding between heavier Group 14 elements and transition metals, has been synthesised and completely characterised by NMR, Raman and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid state.

机译：一种新的三氧锡酸盐-过渡金属络合物{[Li] [（Me-2-NCH2CH2O）（3）Sn-Fe（CO）（4）]}（2）（3），表现出一种不寻常的杂原子键合已经合成了较重的第14组元素和过渡金属，并已通过溶液中的NMR，拉曼和IR光谱以及固态的拉曼光谱和X射线衍射分析进行了完整表征。

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《Dalton transactions: An international journal of inorganic chemistry》 |2008年第9期|共4页
作者
Khrustalev VN; Chernov OV; Aysin RR; Portnyagin IA; Nechaev MS; Bukalov SS;
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正文语种 eng
中图分类无机化学;
关键词
STANNYLENE COMPLEXES; CRYSTAL-STRUCTURES; SN; GE; TIN; GERMANIUM(II); EQUATORIAL; NITROGEN; LIGANDS; TIN(II);

机译：锡烯络合物;晶体结构;SN;GE;锡;锗（II）;赤道;氮;液体;锡（II）;

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1. The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment [J] . Khrustalev VN, Chernov OV, Aysin RR, Dalton transactions: An international journal of inorganic chemistry . 2008,第9期

机译：较重的14族元素与过渡金属之间的异核键合：一种新型的三氧锡酸铁复合物，具有不寻常的锡酸根碎片
2. Heteronuclear bonding between heavier group 14 elements and transition-metals: novel halogermylene- and stannylene transition-metal complexes L-2(X)MM ' L '(n) [L-2 = PhNC(Me)CHC(Me)NPh; X = Cl, I; M = Ge, Sn; M ' L '(n) = W(CO)(5), Fe(CO)(4)] [J] . Saur I., Rima G., Miqueu K., Journal of Organometallic Chemistry . 2003,第1a2期

机译：较重的14族元素与过渡金属之间的异核键合：新型卤化亚甲基和亚锡过渡金属配合物L-2（X）MM'L'（n）[L-2 = PhNC（Me）CHC（Me）NPh; X = Cl，I; M = Ge，Sn; M'L'（n）= W（CO）（5），Fe（CO）（4）]
3. Triple bonds between transition metals and the heavier elements of groups 14 and 15 [J] . Balazs G, Gregoriades LJ, Scheer M Organometallics . 2007,第13期

机译：过渡金属与第14和15组的较重元素之间的三键
4. The Unusual Partial Molar Volumes of Dissolved Neutral Transition Metal Complexes in Organic Solvents [C] . Koon Huat Kuek, Marc Garland AIChE annual meeting . 2003

机译：在有机溶剂中溶解的中性过渡金属配合物的不寻常的部分摩尔体积
5. Synthesis, structures and bonding of superconducting barium vanadium suflide and intermetallic solid state compounds of group 2, 3, 13, 14 and transition elements. [D] . Lobring, Kim Carl. 2001

机译：第2、3、13、14族和过渡元素的超导钡钒硫化物和金属间固态化合物的合成，结构和键合。
6. In-Depth Investigation of a Donor–AcceptorInteraction on the Heavy-Group-14@Group-13-Diyls in Transition-MetalTetrylone Complexes: Structure Bonding and Property [O] . HuynhThi Phuong Loan, Thanh Q. Bui, Tran Thi Ai My, 2020

机译：深入调查供体受体过渡金属中重型-14×13族 - 13-二基的相互作用替纳酮配合物：结构粘合和性质
7. Transition Metal Complexes with the Cyclic Polyene Ligands of the Heavy Group 14 Elements [O] . Lee Vladimir Yaroslavovitch 2012

机译：重族14元素环状多烯配体的过渡金属配合物
8. Bonding Studies of Transition-Metal Complexes. Part II. Helium-1 Photoelectron Spectra of Homoleptic d(0)d(1) and d(10) Tetrakis (Dialkylamides) of Transition and Group 4B Metals and Tungsten Hexakis(Dimethylamide). [R] . Gibbins, S. G., Lappert, M. F., Pedley, J. B., 1974

机译：过渡金属配合物的键合研究。第二部分。 Homoleptic d（0）d（1）和d（10）Tetrakis（二烷基酰胺）的过渡和4B族金属和六氟化钨（二甲基酰胺）的氦-1光电子谱。

The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment

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