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Synthesis and Properties of Metal Poly(butyl acrylate)

机译:金属聚丙烯酸丁酯的合成与性能

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Butyl acrylate colloids were obtained by codeposition at 77 K of the mono-mer with several metals such as Pd,Au,Ag,Cu,Zn,.Cd,Ga,In,Ge,Sn,Sb,AND Bi.The colloids were polymerized with different amountas of an initiator (AIBN) at 65deg for 0.5 h and a wide range of viscosity-average molecular weights (M_V,10~4-10~5 g/mol) were obtained depending upon the metal used.The metal colloid concentration and stability are reported.The thermal stability and metal composition are also described.The polymers are stable even at 400degC.,with Ga-poly(butyl acrylate) being the most stable at 407degC.The metal content ranged between 0 0 and 1.32% w/w for the highest MW fraction and between 0.11 and 1.09% w/w for the lowest MW fraction.Polymers with several colors were obtained depending on the metal used.
机译:丙烯酸丁酯胶体是通过在单体的77 K处与几种金属(例如Pd,Au,Ag,Cu,Zn,Cd,Ga,In,Ge,Sn,Sb和Bi)共沉积获得的。取决于所用金属,在65°C下反应0.5h可得到不同量的引发剂(AIBN),并获得宽范围的粘均分子量(M_V,10〜4-10〜5 g / mol)。还描述了热稳定性和金属组成。该聚合物甚至在400°C时也是稳定的,其中Ga-聚丙烯酸丁酯在407°C时最稳定。金属含量在0 0和1.32%w之间最高的MW分数为/ w,最低的MW分数为0.11至1.09%w / w。根据所使用的金属,可以得到具有几种颜色的聚合物。

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