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Crystal structure of [WI2(CO)(3){P(OMe)(3)}(2)]

机译:[WI2(CO)(3){P(OMe)(3)}(2)]的晶体结构

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WI2(CO)(3){P(OMe)(3)}(2)] crystallizes in the orthorhombic space group Pca2(1), with a = 26.924(5), b = 10.726(2), c = 14.136(3) Angstrom, and Z = 8. There are two molecules in the asymmetric unit, the metal atoms in each case being seven-coordinate with a capped fac-(CO)(3) octahedral geometry. The molecular dimensions in the two molecules are nearly identical. The W-P distance to the capping atom 2.397 Angstrom (average) is significantly shorter than the other W-P distance, 2.525 Angstrom (average). [References: 24
机译:WI2(CO)(3){P(OMe)(3)}(2)]在正交空间群Pca2(1)中结晶,a = 26.924(5),b = 10.726(2),c = 14.136( 3)埃,Z =8。在不对称单元中有两个分子,每种情况下的金属原子为七坐标,且封端的fac-(CO)(3)八面体几何形状。这两个分子的分子尺寸几乎相同。到封端原子的W-P距离2.397埃(平均)明显短于其他W-P距离2.525埃(平均)。 [参考:24

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