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首页> 外文期刊>Journal of Macromolecular Science. Pure and Applied Chemistry >Nanoalloy Based on Clays: Intercalated-Exfoliated Layered Silicate in High Performance Elastomer
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Nanoalloy Based on Clays: Intercalated-Exfoliated Layered Silicate in High Performance Elastomer

机译:基于粘土的纳米合金:高性能弹性体中的插层剥离层状硅酸盐

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摘要

A novel method is described for the preparation of nanocomposites comprising a high performance rubber for tire application and layeredsilicates clay. In this work nanocomposites of solution-styrene butadiene rubber (S-SBR) with montmorillonite layered silicate wereprepared with carboxylated nitrile rubber (XNBR), a polar rubber, as a compatibilizer. A sufficient amount of organomodified layeredsilicate was loaded in carboxylated nitrile rubber (XNBR) and this compound was blended as a master batch in the S-SBR. Mixed inter-calated/exfoliated morphologies in the nanocomposite are evinced by X-ray diffraction measurements and transmission electronmicroscopy. Dynamic mechanical analysis also supports the compatibility of the composites. A good dispersion of the layered silicatein the S-SBR matrix was reflected from the physical properties of the nanocomposites, especially in terms of tensile strength and highelongation properties.
机译:描述了一种用于制备纳米复合材料的新方法,该复合材料包括用于轮胎的高性能橡胶和层状硅酸盐粘土。在这项工作中,溶液型丁苯橡胶(S-SBR)与蒙脱土层状硅酸盐的纳米复合材料是用羧化丁腈橡胶(XNBR)(一种极性橡胶)作为增容剂制备的。将足够量的有机改性的层状硅酸盐装载到羧化丁腈橡胶(XNBR)中,并将该化合物作为母料掺入S-SBR中。通过X射线衍射测量和透射电子显微镜证实了纳米复合材料中混合的插层/剥离的形态。动态力学分析也支持复合材料的相容性。层状硅酸盐在S-SBR基质中的良好分散性反映在纳米复合材料的物理性能上,特别是在拉伸强度和高伸长率方面。

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