首页> 外文期刊>Journal of Physical and Chemical Reference Data >PHASE DIAGRAMS AND THERMODYNAMIC PROPERTIES OF BINARY AND TERNARY SYSTEMS BASED ON NITROAROMATIC COMPOUNDS [Review]
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PHASE DIAGRAMS AND THERMODYNAMIC PROPERTIES OF BINARY AND TERNARY SYSTEMS BASED ON NITROAROMATIC COMPOUNDS [Review]

机译:基于亚硝基化合物的二元和三元体系的相图和热力学性质[综述]

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The phase diagram data of 226 binary organic systems based on nitroaromatic compounds were critically evaluated with the aid of a computer-coupled thermodynamic/phase diagram analysis. The results of this analysis include the excess Gibbs energies of all solution phases as well as the Gibbs energies of fusion and formation of intermediate compounds. These quantities were used to calculate a best phase diagram for each system. The phase diagrams of seven ternary systems were calculated from the evaluated thermodynamic data of the binary subsystems with the use of the Kohler interpolative model and compared with the experimental diagrams. (C) 1997 American Institute of Physics and American Chemical Society. [References: 146]
机译:借助于计算机耦合的热力学/相图分析,对基于硝基芳族化合物的226种二元有机体系的相图数据进行了严格评估。该分析的结果包括所有溶液相的过量吉布斯能量以及聚变和中间化合物形成的吉布斯能量。这些数量用于计算每个系统的最佳相位图。使用科勒插值模型,根据二元子系统的热力学数据,计算出七个三元体系的相图,并与实验图进行比较。 (C)1997年美国物理研究所和美国化学学会。 [参考:146]

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