Ion hydration and large electrocaloric effect

Danielewicz-Ferchmin I.; Ferchmin AR.

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Ion hydration and large electrocaloric effect

机译：离子水合和大电热效应

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Starting from a discussion of the grand potential change associated with introduction of ions into water, the electrocaloric effect for the system ion-surrounding water is calculated by means of this recent statistical approach to the problem of water in a high electric field. It is concluded that this effect is essential for the hydration of ions, in particular, for the heat of solution of salts. Consistency between the present approach and recent literature results of a density functional calculation, as well as experimental data for sequential enthalpies of hydration of doubly charged ions in the gas phase, is discussed. [References: 35]

机译：从对与将离子引入水中有关的巨大电势变化的讨论开始，借助这种针对高电场中水问题的最新统计方法，计算了系统离子包围水的电热效应。结论是该作用对于离子的水合作用，特别是对于盐溶液的热是必不可少的。讨论了当前方法与密度函数计算的最新文献结果之间的一致性，以及气相中双电荷离子水合的顺序焓的实验数据。 [参考：35]

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《Journal of Solution Chemistry》 |2002年第1期|共16页
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Danielewicz-Ferchmin I.; Ferchmin AR.;
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Ion hydration and large electrocaloric effect

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