Lanthanide dithiocarbamate complexes: Efficient catalysts for the cyanosilylation of aldehydes

Vale JA; Faustino WM; Menezes PH; de Sa GF

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Lanthanide dithiocarbamate complexes: Efficient catalysts for the cyanosilylation of aldehydes

机译：镧系元素二硫代氨基甲酸酯配合物：醛氰基硅烷化的高效催化剂

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摘要

A new class of lanthanide dithiocarbamate complexes was used to promote the cyanosilylation of aldehydes at high yields at room temperature. This represents the first application of lanthanide dithiocarbamate acting as Lewis acid.

机译：新型的镧系元素二硫代氨基甲酸酯络合物用于在室温下以高收率促进醛的氰基硅烷化。这代表了用作路易斯酸的镧系元素二硫代氨基甲酸酯的首次应用。

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《Journal of the Brazilian Chemical Society》 |2006年第5期|共3页
作者
Vale JA; Faustino WM; Menezes PH; de Sa GF;
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正文语种 eng
中图分类化学;
关键词
lanthanide dithiocarbamate; cyanosilylation; Lewis acid; cyanohydrins; CHIRAL LEWIS-BASE; TRIMETHYLSILYL CYANIDE; TITANIUM COMPLEXES; ENANTIOSELECTIVE TRIMETHYLSILYLCYANATION; ASYMMETRIC ADDITION; CARBONYL-COMPOUNDS; KETONES; CYANOHYDRINS; SILYLCYANATION; ACIDS;

机译：镧系元素二硫代氨基甲酸酯;氰基硅烷化;路易斯酸;氰醇;手性路易斯碱;三甲基甲硅烷基氰化物;钛络合物;对映体选择性三乙二甲基硅烷化;不对称加成;羰基化合物;酮;氰基化;

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专利

1. Lanthanide dithiocarbamate complexes: efficient catalysts for the cyanosilylation of aldehydes [J] . Gilberto F. De Sá, Juliana A. Vale, Paulo H. Menezes, Journal of the Brazilian Chemical Society . 2006,第5期

机译：镧系二硫代氨基甲酸酯络合物：醛氰基硅烷化的有效催化剂
2. Lanthanide anilido complexes: synthesis, characterization, and use as highly efficient catalysts for hydrophosphonylation of aldehydes and unactivated ketones [J] . Chengwei Liu, Qinqin Qian, Kun Nie, Dalton transactions: An international journal of inorganic chemistry . 2014,第22期

机译：镧系苯胺复合物：合成，表征和用作醛和未活化酮的氢膦酰化的高效催化剂
3. Anionic Bridged Bis(amidinate) Lithium Lanthanide Complexes: Efficient Bimetallic Catalysts for Mild Amidation of Aldehydes with Amines [J] . Junfeng Wang, Junmei Li, Fan Xu Advanced synthesis & catalysis . 2009,第9期

机译：阴离子桥联双（酰胺基）镧系锂配合物：高效的双金属催化胺与胺的轻度酰胺化
4. Divalent lanthanide complexes as a signle catalyst for acrylonitrile polymerization [C] . Taiqi Liu, Youliang Hu Pacific polymer conference preprints . 1999

机译：二价镧系元络合物作为丙烯腈聚合的单一催化剂
5. I. Stereochemistry of cyclopropane formation involving group (IV) organometallic complexes. II. Slower stoichiometric and faster catalytic reduction of aldehydes by the PPh(3) substituted hydroxycyclopentadienyl ruthenium hydride [2,5-Ph(2)-3,4-Tol(2)(eta(5)-C(4)COH)]Ru(CO)(PPh(3))H: A highly chemoselective catalyst for hydrogenation of aldehydes over ketones. [D] . Strotman, Neil Adham. 2005

机译：I.涉及（IV）族有机金属配合物的环丙烷形成的立体化学。二。由PPh（3）取代的羟基环戊二烯基氢化钌[2,5-Ph（2）-3,4-Tol（2）（eta（5）-C（4）COH）] Ru的化学计量较慢和较快的醛催化还原（CO）（PPh（3））H：一种高度化学选择性的催化剂，用于醛在酮上的氢化。
6. Tris(246-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones [O] . Satoru Matsukawa, Izumi Sekine, Ayumi Iitsuka 2009

机译：三（246-三甲氧基苯基）膦（TTMPP）：醛和酮的氰基硅烷化和氰基碳酸化的高效催化剂
7. Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): Efficient Catalysts for the Cyanosilylation and Cyanocarbonation of Aldehydes and Ketones [O] . Satoru Matsukawa, Izumi Sekine, Ayumi Iitsuka 2009

机译：三（2,4,6-三甲氧基苯基）膦（TTmpp）：用于醛和酮的氰基甲硅烷基化和氰基化的高效催化剂

Lanthanide dithiocarbamate complexes: Efficient catalysts for the cyanosilylation of aldehydes

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