SYNTHESIS AND MAGNETIС PROPERTIES OF A NEW BINUCLEAR COPPER(II) COMPLEX WITH NAPHTHALATO-BRIDGED LIGAND

REN S.; XIA P.; MA B.; HE Y.F.; YANG Y.; TANG M.Y.; MA S.L.

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SYNTHESIS AND MAGNETIС PROPERTIES OF A NEW BINUCLEAR COPPER(II) COMPLEX WITH NAPHTHALATO-BRIDGED LIGAND

机译：新型萘型桥联配体双核铜（II）配合物的合成及磁性能

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To utilized a bridged-ligand of 1,8-naphthalate dianion (NAPH) as building block by self-assembly technology, a new binuclear copper(II) compound [Cu_2(μ-NAPH)_2(DMF)_2(H_2O)_2] (I) has been constructed and structurally characterized by X-ray crystallography. Complex I crystallizes in monoclinic, space group C2/c, with a = 17.822(9), b = 9.964(5), c = 23.194(11) ? and β= 102.385(5)°. Magnetic measurements confirm that I presents a very weak antiferromagnetic interaction between the paramagnetic ions.

机译：以自组装技术以1,8-萘二甲酸酯双桥配体作为构建基，开发了一种新的双核铜（II）化合物[Cu_2（μ-NAPH）_2（DMF）_2（H_2O）_2]。（I）已经通过X射线晶体学构造并在结构上表征。配合物I在单斜晶体C2 / c空间群中结晶，a = 17.822（9），b = 9.964（5），c = 23.194（11）？ β= 102.385（5）°。磁测量结果证实，我在顺磁离子之间呈现非常弱的反铁磁相互作用。

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《Координационная химия》 |2013年第8期|共4页
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REN S.; XIA P.; MA B.; HE Y.F.; YANG Y.; TANG M.Y.; MA S.L.;
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1. SYNTHESIS AND MAGNETIС PROPERTIES OF A NEW BINUCLEAR COPPER(II) COMPLEX WITH NAPHTHALATO-BRIDGED LIGAND [J] . REN S., XIA P., MA B., Координационная химия . 2013,第8期

机译：新型萘型桥联配体双核铜（II）配合物的合成及磁性能
2. Synthesis and Magnetic Properties of a New Binuclear Copper(II) Complex with Naphthalato-Bridged Ligand~1 [J] . S. Ren, P. Xia, B. Ma Russian Journal of Coordination Chemistry . 2013,第8期

机译：新型萘二甲酰胺桥联配体〜1的双核铜（II）配合物的合成与磁性
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SYNTHESIS AND MAGNETIС PROPERTIES OF A NEW BINUCLEAR COPPER(II) COMPLEX WITH NAPHTHALATO-BRIDGED LIGAND

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