The phenalenyl motf: A magnetic chameleon

Cyranski MK; Havenith RWA; Dobrowolski MA; Gray BR; Krygowski TM; Fowler PW; Jenneskens LW

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The phenalenyl motf: A magnetic chameleon

机译：苯并菲基尔：磁性变色龙

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The 12 pi cation (3) and 14 pi anion (4) derived from the phenalenyl radical (2) support diatropic ("aromatic") perimeter ring currents, but isoelectronic replacement of the central atom by either boron (5) or nitrogen (6) leads to paratropic ("antiaromatic") current; the ipsocentric approach to molecular magnetic response accounts for all four patterns in terms of competition between translationally and rotationally allowed virtual pi-pi* excitations.

机译：衍生自苯二烯基（2）的12π阳离子（3）和14 pi阴离子（4）支持变径（“芳族”）周环电流，但中心原子被硼（5）或氮（6）等电取代。）导致顺流（“反芳香”）电流;就平移和旋转允许的虚拟pi-pi *激发之间的竞争而言，分子中心反应的ipsocentric方法解决了所有四种模式。

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《Chemistry: A European journal》 |2007年第8期|共7页
作者
Cyranski MK; Havenith RWA; Dobrowolski MA; Gray BR; Krygowski TM; Fowler PW; Jenneskens LW;
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正文语种 eng
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ab initio calculations; aromaticity; Huckel theory; phenalenes; ring currents; AROMATIC STABILIZATION ENERGIES; INDEPENDENT CHEMICAL-SHIFTS; RING CURRENT ANALYSIS; PI-ELECTRON SYSTEMS; BIOT-SAVART LAW; BRIDGEHEAD NITROGEN; RESPONSE PROPERTIES; TRIPLET-STATES; ANNULENES; CHEMISTRY;

机译：从头计算;芳香性;Huckel理论;菲涅尔;环电流;芳族稳定能;独立的化学位移;环电流分析;PI电子系统;BOT-SAVART定律;桥头氮;响应特性;三态;应力;

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1. The phenalenyl motf: A magnetic chameleon [J] . Cyranski MK, Havenith RWA, Dobrowolski MA, Chemistry: A European journal . 2007,第8期

机译：苯并菲基尔：磁性变色龙
2. o-Quinone phenalenyl derivatives as expedient ligands for the design of magnetically active metal complexes: A computational study [J] . Chemical Physics Letters . 2020,第期

机译：O-醌酚烯基衍生物作为用于设计磁活性金属配合物的方便配体：计算研究
3. Counting the Zero Modes and Magnetic Moment by Topology of a Phenalenyl-Tessellation Molecule with Vacancies [J] . Journal of the Physical Society of Japan . 2019,第12期

机译：通过空位的酚蛋白胸骨分子的拓扑计数零模式和磁矩
4. Dimerization Transition in Phenalenyl-based Neutral Radicals at High Magnetic Fields [C] . G. A. Jorge, K. H. Kim, M. Jaime, International Conference on Low Temperature Physics . 2005

机译：高磁场酚烯基中性自由基中的二聚化转变
5. Synthesis, characterization and properties of phenalenyl-based neutral radical molecular conductors. [D] . Liao, Puhong. 2007

机译：苯酚基中性自由基分子导体的合成，表征和性能。
6. Characterization of Metarhizium viride Mycosis in Veiled Chameleons (Chamaeleo calyptratus) Panther Chameleons (Furcifer pardalis) and Inland Bearded Dragons (Pogona vitticeps) [O] . Volker Schmidt, Linus Klasen, Juliane Schneider, 2017

机译：在面纱变色龙（Chamaeleo calyptratus）黑豹变色龙（Furcifer pardalis）和内陆有胡子龙（Pogona vitticeps）中变绿变菌霉菌病的特征
7. The phenalenyl motif: a magnetic chameleon [O] . Havenith, R.W.A., Dobrowolski, M.A., Gray, B.R., 2007

机译：phenalenyl motif：磁性变色龙

The phenalenyl motf: A magnetic chameleon

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