Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles: Ligand effects and solvent-controlled product formation

Fetz M.; Gerber R.; Blacque O.; Frech C.M.

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Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles: Ligand effects and solvent-controlled product formation

机译：氨基膦稳定的铑纳米粒子前体催化氨硼烷的水解：配体效应和溶剂控制的产物形成

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Releasing hydrogen: Aminophosphine complexes of rhodium are excellent systems for the hydrolysis of H_3N-BH_3. The release of H_2 in THF/H_2O mixtures generates NH_3 and B(OH)_3 and is based on the sequential catalytic dehydrogenation of H_3N-BH_(3-n)(OH)_n and hydrolysis of H _2N=BH_(2-n)(OH)_n (n=0-2, see scheme).

机译：释放氢：铑的氨基膦配合物是水解H_3N-BH_3的极佳系统。 H_2在THF / H_2O混合物中的释放会产生NH_3和B（OH）_3，并且基于H_3N-BH_（3-n）（OH）_n的顺序催化脱氢和H _2N = BH_（2-n）的水解（OH）_n（n = 0-2，请参阅方案）。

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《Chemistry: A European journal》 |2011年第17期|共5页
作者
Fetz M.; Gerber R.; Blacque O.; Frech C.M.;
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正文语种 eng
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aminophosphines; ammonia boranes; dehydrogenation; dihydrogen; hydrolysis; rhodium;

机译：氨基膦;硼烷氨;脱氢;二氢;水解;铑;

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1. Hydrolysis of Ammonia Borane Catalyzed by Aminophosphine-Stabilized Precursors of Rhodium Nanoparticles: Ligand Effects and Solvent-Controlled Product Formation [J] . Marco Fetz Roman Gerber Dr. Olivier Blacque Dr. Christian M. Frech Chemistry - A European Journal . 2011,第17期

机译：氨基膦稳定的铑纳米颗粒前体催化氨硼烷的水解：配体效应和溶剂控制的产物形成
2. Ultrasmall rhodium nanoclusters anchored on nitrogen-doped carbon nanotubes with embedded nickel nanoparticles as magnetically recyclable catalysts for efficient ammonia-borane hydrolysis [J] . International journal of hydrogen energy . 2020,第3期

机译：超小型铑纳米簇固定在掺氮的碳纳米管上，具有嵌入的镍纳米颗粒，可作为磁性可循环利用的催化剂，用于有效地氨-硼烷水解
3. Facile and eco-friendly synthesis of porous carbon nanosheets as ideal platform for stabilizing rhodium nanoparticles in efficient hydrolysis of ammonia borane [J] . Lin Hongqiao, Xu Caili, Wang Qi, International journal of hydrogen energy . 2019,第39期

机译：便捷，环保的多孔碳纳米片合成，是稳定氨硼烷有效水解铑纳米粒子的理想平台
4. Ca_(0.5)Mg_(0.5)Co_2O_4 Nanosheets Comprised of Nanoparticles, Synthesis, Characterization and their Catalytic Activity in the Hydrolysis of Ammonia Borane for Hydrogen Production [C] . Liling LI, Xiuxia FENG, Jinyun LIAO, International Conference on Material Engineering and Application . 2018

机译：CA_（0.5）Mg_（0.5）CO_2O_4纳米蛋白酶组成，其组成纳米颗粒，合成，表征及其催化活性，用于氢生产的氨硼烷的水解中
5. Synthesis of C2-symmetric P-chiral bis(phosphine borane)s and their application in rhodium(I) catalyzed asymmetric transformation. [D] . Heath, Holly Ann. 2001

机译：C2-对称的P-手性双（膦硼烷）的合成及其在铑（I）催化的不对称转化中的应用。
6. Covalent triazine framework supported non-noble metal nanoparticles with superior activity for catalytic hydrolysis of ammonia borane: from mechanistic study to catalyst design [O] . Zhao Li, Teng He, Lin Liu, 2017

机译：共价三嗪骨架负载的非贵金属纳米颗粒具有优异的催化氨硼烷水解的能力：从机理研究到催化剂设计
7. Efficient Hydrolysis of Ammonia Borane for Hydrogen Evolution Catalyzed by Plasmonic Ag@Pd CoreShell Nanocubes [O] . -1

机译：PD CoreShell纳米尺寸催化催化氢硼烷的高效水解

Hydrolysis of ammonia borane catalyzed by aminophosphine-stabilized precursors of rhodium nanoparticles: Ligand effects and solvent-controlled product formation

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