Dinuclear copper(I) thiolate complexes with a bridging noninnocent PNP ligand

Van Der Vlugt J.I.; Pidko E.A.; Bauer R.C.; Gloaguen Y.; Rong M.K.; Lutz M.

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Dinuclear copper(I) thiolate complexes with a bridging noninnocent PNP ligand

机译：具有桥接非纯PNP配体的双核硫醇铜（I）配合物

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Noninnocent, but not guilty: The versatile PNPtBu scaffold acts as a noninnocent, pseudobridging ligand toward CuX (ratio 1:2), resulting in a 1D-coordination chain. Ligand dearomatization by using base and subsequent addition of thiols leads to the unique, asymmetrically substituted, dinuclear Cu species with reactive Br coligands and the versatile PNPtBu ligand that bridges the two Cu centers (see scheme).

机译：非清白但无罪：多功能的PNPtBu支架充当CuX的非清白假桥配体（比率1：2），从而形成一维配位链。通过使用碱和随后添加硫醇进行的配体脱芳香化作用，会导致独特的，不对称取代的，双核的铜物种具有反应性大肠埃希菌和连接两个铜中心的通用PNPtBu配体（参见方案）。

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《Chemistry: A European journal》 |2011年第14期|共5页
作者
Van Der Vlugt J.I.; Pidko E.A.; Bauer R.C.; Gloaguen Y.; Rong M.K.; Lutz M.;
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正文语种 eng
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关键词
bridging ligands; copper; dearomatization; noninnocent ligands; thiolates;

机译：桥连配体;铜;脱芳构;非纯配体;硫醇盐;

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1. Dinuclear Copper(I) Thiolate Complexes with a Bridging Noninnocent PNP Ligand [J] . Dr. Jarl Ivar van der Vlugt, Dr. Evgeny A. Pidko, Dr. Richard C. Bauer, Chemistry - A European Journal . 2011,第14期

机译：双核非纯PNP配体的双核硫醇铜（I）配合物
2. WHEN IS AN ODD-ELECTRON DINUCLEAR COMPLEX A MIXED-VALENT SPECIES - TUNING OF LIGAND-TO-METAL SPIN SHIFTS IN DIRUTHENIUM(III,II) COMPLEXES OF NONINNOCENT BRIDGING LIGANDS OC(R)NNC(R)O [J] . Kasack V., Binder H., Jordanov J., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第7期

机译：当奇数电子络合物为混合价物种时-非纯桥连配体OC（R）NNC（R）O的D（III，II）络合物中配体至金属自旋碎片的调节
3. Dinuclear cyano complexes of cobalt(III) and iron(III) containing noninnocent 1,2,4,5-tetrakis(2-pyridinecarboxamido)benzene bridging ligands [J] . Beckmann U., Bill E., Weyhermuller T., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2003,第4期

机译：含非纯1,2,4,5-四（2-吡啶甲酰胺基）苯桥联配体的钴（III）和铁（III）的双核氰基配合物
4. Thiolate-Bridged Iron-Nickel Dinuclear Complexes Modeling the Active Site of NiFe Hydrogenases [C] . Yasuhiro Ohki, Zilong Li, Katsuaki Kuge, Symposium on Organometallic Chemistry . 2004

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5. SYNTHESIS AND REACTIONS OF DINUCLEAR TRANSITION METAL COMPLEXES CONTAINING BRIDGING LIGANDS RELEVANT TO HETEROGENEOUS CATALYSIS. [D] . JACOBSEN, ERIC NIELS. 1986

机译：包含与非均相催化有关的桥连配体的核过渡金属配合物的合成和反应。
6. Controlled Interconversion of a Dinuclear Au Species Supported by a Redox‐Active Bridging PNP Ligand Facilitates Ligand‐to‐Gold Electron Transfer [O] . Dr. Vincent Vreeken, Dr. Maxime A. Siegler, Dr. Ir. Jarl Ivar van der Vlugt -1

机译：氧化还原活性桥联PNP配体支持的双核金物种的受控互变促进配体到金的电子转移
7. Facile S-S Bond Activation of Alkyl and Aryl Disulfides by RuCp(CH3CN)3+: Formation of Dinuclear Ru(III)-Ru(III) Complexes with Bridging Thiolate Ligands [O] . -1

机译：通过RUCP（CH3CN）3+的烷基和芳基二硫化芳基的容易S-S键活化：用桥接硫醇酸盐配体形成二核Ru（III）-RU（III）复合物
8. Preparation and Reactions of Tantalum Alkylidene Complexes Containing Bulky Phenoxide or Thiolate Ligands. Controlling Ring-Opening Metathesis Polymerization Activity and Mechanism Through Choice of Anionic Ligand [R] . Wallace, K. C., Liu, A. H., Dewan, J. C., 1988

机译：含大量酚盐或硫醇盐配体的亚钽基亚砜配合物的制备及反应。通过选择阴离子配体控制开环易位聚合活性及机理

Dinuclear copper(I) thiolate complexes with a bridging noninnocent PNP ligand

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