Fe-catalyzed thioesterification of carboxylic esters

Magens S.; Plietker B.

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Fe-catalyzed thioesterification of carboxylic esters

机译：铁催化的羧酸酯的硫酯化

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Second nature: Starting from shelf-stable aryl esters and thiols, a variety of carboxylic acid esters were transformed into the corresponding thioesters with no racemization of labile stereocenters (see scheme). The method was successfully applied in a native chemical-ligation-type peptide formation, which suggests that the thiol may act as a co-catalyst for future 1,2-additions of pronucleophiles to carboxylic esters.

机译：第二性质：从稳定的芳基酯和硫醇开始，各种羧酸酯被转化为相应的硫酯，而没有外消旋的立体中心（见方案）。该方法已成功地应用于天然化学连接型肽的形成，这表明硫醇可能充当亲核试剂未来向羧酸酯中1,2-加成的助催化剂。

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《Chemistry: A European journal》 |2011年第32期|共3页
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Magens S.; Plietker B.;
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正文语种 eng
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amides; catalysis; iron; peptides; sulfur; thioester;

机译：酰胺;催化;铁;肽;硫;硫酯;

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专利

1. Fe-Catalyzed Thioesterification of Carboxylic Esters [J] . Dipl.-Chem. Silja Magens Prof. Dr. Bernd Plietker Chemistry - A European Journal . 2011,第32期

机译：铁催化的羧酸酯的硫酯化
2. Flavouring Group Evaluation 62 Rev1 (FGE.62 Rev1): Consideration of of linear and branched‐chain aliphatic unsaturated, unconjugated alcohols, aldehydes, acids, and related esters evaluated by JECFA (61st and 68th meeting) structurally related to branched‐ and straight‐chain unsaturated carboxylic acids and esters of these with aliphatic saturated alcohols evaluated by EFSA in FGE.05Rev2 (2010) and to straight‐ and branched‐chain aliphatic unsaturated primary alcohols, aldehydes, carboxylic acids, and esters evaluated by EFSA in FGE.06Rev1 (2008) [J] . EFSA Journal . 2010,第11期

机译：香精基团评估报告62 Rev1（FGE.62 Rev1）：考虑了由JECFA评估的直链和支链脂族不饱和，未共轭的醇，醛，酸和相关酯（61 st 和68
3. Microwave-Assisted Direct Thioesterification of Carboxylic Acids [J] . Chou Yen-Lin, Jhong Yi, Swain Sharada Prasanna, The Journal of Organic Chemistry . 2017,第19期

机译：微波辅助羧酸的直接硫酯化
4. Influence of Carboxylic Acid-Carboxylic Ester Ratio of Carboxylic Acid Ester Superplasticizer on Characteristics of Cement Mixtures [C] . G. Ferrari, T. Cerulli, P. Clemente, CANMET/ACI international conference on superplasticizers and other chemical admixtures in concrete . 2000

机译：羧酸酯高效减水剂的羧酸酯比对水泥混合料性能的影响
5. Relationship between ligand structure and reactivity for copper(II) complex mediated hydrolysis of phosphate diesters, carboxylic esters, and amides. Part~I. Hydrolysis of phosphate diesters promoted by copper(II) complexes. Part~II. Hydrolysis of carboxylic esters and amides catalyzed by copper(II) complexes. [D] . Jubian, Vrej. 1991

机译：铜（II）配合物介导的磷酸二酯，羧酸酯和酰胺水解的配体结构与反应性之间的关系。第一部分铜（II）配合物促进的磷酸二酯的水解。第二部分铜（II）配合物催化的羧酸酯和酰胺的水解。
6. Scientific Opinion on Flavouring Group Evaluation 5 Revision 3 (FGE.05Rev3): Branched‐ and straight‐chain unsaturated aldehydes dienals unsaturated and saturated carboxylic acids and related esters with saturated and unsaturated aliphatic alcohols and a phenylacetic acid related ester from chemical groups 1 2 3 5 and 15 [O] . EFSA Food Additives and Flavourings (FAF), Maged Younes, Gabriele Aquilina, 2019

机译：关于调味剂基团评估5的科学意见修订版3（FGE.05Rev3）：支链和直链不饱和醛二烯不饱和和饱和羧酸及相关酯与饱和和不饱和脂族醇以及化学基团与苯乙酸有关的酯1、2、3、5和15
7. 2-Hydroxy-3-oxo-2,3-dihydrofuran-2-carboxylic Ester: The Oxidation Product of 3-Hydroxyfuran-2-carboxylic Ester [O] . Hisashi Takei, Teruaki Mukaiyama 1970

机译：2-羟基-3-氧代-2,3-二氢呋喃-2-羧酸酯：3-羟基呋喃-2-羧酸酯的氧化产物

Fe-catalyzed thioesterification of carboxylic esters

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