Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: A simple approach to allylic trifluoromethylation

Miyake Y.; Ota S.-I.; Nishibayashi Y.

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Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: A simple approach to allylic trifluoromethylation

机译：铜催化烯丙基卤的亲核三氟甲基化：烯丙基三氟甲基化的简单方法

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Trifluoromethylation: The treatment of allylic halides with trifluoromethyltrimethylsilane in the presence of a catalytic amount of copper(I) thiophene-2-carboxylate (CuTC) gives the corresponding allylic trifluoromethylation products in good to high yields and with complete regioselectivity (see scheme). The use of THF as a solvent is crucial for obtaining good yields of product.

机译：三氟甲基化：在催化量的噻吩-2-羧酸铜（I）存在下，用三氟甲基三甲基硅烷处理烯丙基卤化物可得到相应的烯丙基三氟甲基化产物，产率高至高且具有完全的区域选择性（参见方案）。使用THF作为溶剂对于获得良好的产物收率至关重要。

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《Chemistry: A European journal》 |2012年第42期|共4页
作者
Miyake Y.; Ota S.-I.; Nishibayashi Y.;
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正文语种 eng
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allylic compounds; copper; fluorine; homogeneous catalysis; trifluoromethylation;

机译：烯丙基化合物;铜;氟;均相催化;三氟甲基化;

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1. Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: A simple approach to allylic trifluoromethylation [J] . Miyake Y., Ota S.-I., Nishibayashi Y. Chemistry: A European journal . 2012,第42期

机译：铜催化烯丙基卤的亲核三氟甲基化：烯丙基三氟甲基化的简单方法
2. Copper-Catalyzed Trifluoromethylation of Trisubstituted Allylic and Homoallylic Alcohols [J] . Lei Jian, Liu Xiaowu, Zhang Shaolin, Chemistry: A European journal . 2015,第18期

机译：铜催化三取代的烯丙基和均烯丙基醇的三氟甲基化
3. Copper-catalyzed decarboxylative trifluoromethylation of allylic bromodifluoroacetates [J] . Ambler B.R., Altman R.A. Organic letters . 2013,第21期

机译：铜催化的烯丙基溴二氟乙酸酯的脱羧三氟甲基化
4. Nucleophilic and Electrophilic Fluorination and Trifluoromethylation of Organic Compounds [C] . Jeanne M. Shreeve Sino-Japan Conference of Fluorochemical Engineering amp; Fine Chemicals(FChina2001); 20010522-26; Xi'an(CN) . 2001

机译：有机化合物的亲核和亲电氟化和三氟甲基化
5. Nucleophilic reductions of sulfonate esters of oxiranemethanols and aziridinemethanols by the telluride ion to give allylic alcohols and allylic amines [D] . Pepito, Maria Aurora Ammie Fay Sanchez 1996

机译：碲化物离子对环氧乙烷甲醇和氮丙啶甲醇的磺酸酯进行亲核还原，得到烯丙基醇和烯丙基胺
6. Copper-Catalyzed Decarboxylative Trifluoromethylation of Allylic Bromodifluoroacetates [O] . Brett R. Ambler, Ryan A. Altman -1

机译：铜催化的二氟溴二氟乙酸酯的脱羧三氟甲基化
7. Copper-Catalyzed Asymmetric Allylic Alkylation of β-Keto Esters with Allylic Alcohols [O] . Trillo Alarcón, María Paz, Baeza, Alejandro 2017

机译：铜催化β-酮基酯与烯丙醇的不对称烯丙基烷基化

Copper-catalyzed nucleophilic trifluoromethylation of allylic halides: A simple approach to allylic trifluoromethylation

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