Multicomponent assembly of macrocycles and polymers by coordination of pyridyl ligands to 1,4-bis(benzodioxaborole)benzene

Icli B.; Solari E.; Kilbas B.; Scopelliti R.; Severin K.

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Multicomponent assembly of macrocycles and polymers by coordination of pyridyl ligands to 1,4-bis(benzodioxaborole)benzene

机译：通过吡啶基配体与1,4-双（苯并二恶唑硼烷）苯的配位，将大环化合物和聚合物进行多组分组装

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Multicomponent reactions between 1,4-benzenediboronic acid, catechol, and different pyridyl ligands are reported. The condensation of 1,4-benzenediboronic acid with catechol gives 1,4-bis(benzodioxaborole)benzene. Upon crystallization, the ester aggregates with the N-donor ligands through dative B-N bonds. Depending on the nature of the pyridyl ligand, molecularly defined macrocycles or polymeric structures are obtained. 1D polymers are formed with 4,4-bipyridine and 1,2-di(4-pyridyl)ethylene, whereas a 2D network is obtained with the tetradentate ligand tetra(4-pyridylphenyl)ethylene. These results highlight the utility of dative B-N bonds in structural supramolecular chemistry and crystal engineering. Macrocyclic or polymeric structures were formed from the reactions between 1,4-benzenediboronic acid, catechol, and di-, tri-, and tetratopic pyridyl ligands (see figure). These results demonstrate the utility of dative B-N bonds in structural supramolecular chemistry and crystal engineering.

机译：报道了1，4-苯二硼酸，儿茶酚和不同吡啶基配体之间的多组分反应。 1，4-苯二硼酸与邻苯二酚的缩合得到1，4-双（苯并二恶唑硼烷）苯。结晶后，该酯与N-供体配体通过固定的B-N键聚集。根据吡啶基配体的性质，获得分子定义的大环或聚合物结构。一维聚合物由4,4-联吡啶和1,2-二（4-吡啶基）乙烯形成，而四齿配体四（4-吡啶基苯基）乙烯获得2D网络。这些结果突出了在结构上的超分子化学和晶体工程中，B-N键合的作用。大环或聚合物结构是由1,4-苯二硼酸，邻苯二酚与二，三和四吡啶基配位体之间的反应形成的（见图）。这些结果证明了B-N键在结构超分子化学和晶体工程中的实用性。

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《Chemistry: A European journal》 |2012年第46期|共8页
作者
Icli B.; Solari E.; Kilbas B.; Scopelliti R.; Severin K.;
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正文语种 eng
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boronic acids; dative bonds; macrocycles; polymers; supramolecular chemistry;

机译：硼酸;键;大环;聚合物;超分子化学;

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1. Multicomponent assembly of macrocycles and polymers by coordination of pyridyl ligands to 1,4-bis(benzodioxaborole)benzene [J] . Icli B., Solari E., Kilbas B., Chemistry: A European journal . 2012,第46期

机译：通过吡啶基配体与1,4-双（苯并二恶唑硼烷）苯的配位，将大环化合物和聚合物进行多组分组装
2. Coordination-Driven Self-Assembly of Macrocycles and 1D or 2D Coordination Polymers Using Heteroditopic Pyridyl-Carboxylate Ligands: The Case Study of 5-[(E)-2-(3-Pyridyl)-1-Diazenyl]-2-Hydroxybenzoate in Combination with {RnSn} (n=2 and 3) [J] . Baul Tushar S. Basu, Chaurasiya Anurag, Duthie Andrew, Crystal growth & design . 2019,第11期

机译：使用异分散吡啶基羧酸盐配体的协调驱动的自组装和1D或2D配位聚合物：组合中5 - [（e）-2-（3-吡啶基）-1-二苯基] -2-羟基苯甲酸盐的情况使用{rnsn}（n = 2和3）
3. Neutral coordination polymers based on a metal-mono(dithiolene) complex: Synthesis, crystal structure and supramolecular chemistry of [Zn(dmit)(4,4′-bpy)]_n, [Zn(dmit)(4,4′-bpe)]_n and [Zn(dmit)(bix)]_n (4,4′-bpy = 4,4′-bipyridine, 4,4′-bpe = trans-1,2-bis(4-pyridyl)ethene, bix = 1,4-bis(imidazole-1- ylmethyl)-benzene [J] . Madhu V., Das S.K. Dalton transactions: An international journal of inorganic chemistry . 2011,第48期

机译：基于金属-单（二硫醇）配合物的中性配位聚合物：[Zn（dmit）（4,4'-bpy）] _ n，[Zn（dmit）（4,4'-bpe）的合成，晶体结构和超分子化学）] _ n和[Zn（dmit）（bix）] _ n（4,4'-bpy = 4,4'-联吡啶，4,4'-bpe =反-1,2-双（4-吡啶基）乙烯， bix = 1,4-双（咪唑-1-基甲基）苯
4. Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer Co_3(bpd)_(5.5)(NCS)_6(NH_3)_n·2H_2O (bpd= 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) [C] . Yuqi Liu, Yong Yang, Rui Yang, International Conference on Chemical Engineering, Metallurgical Engineering and Metallic Materials . 2013

机译：柔性配体配位聚合物的合成和晶体结构CO_3（BPD）_（5.5）（NCS）_6（NH_3） _ N·2H_2O（BPD = 1,4-双（4-吡啶基）-2,3-第二次 - 1,3-丁二烯）
5. Construction of Supramolecular and Coordination Compounds from Pyridyl Bis-Urea Macrocycles [D] . Som, Bozumeh 2018

机译：吡啶基双尿素大环化合物的超分子和配位化合物的构建
6. Metal and Ligand Effects on the Construction of Divalent Coordination Polymers Based on bis-Pyridyl-bis-amide and Polycarboxylate Ligands [O] . Miao-Ning Chang, Xiang-Kai Yang, Pradhumna Mahat Chhetri, 2011

机译：金属和配体对基于双吡啶基双酰胺和多羧酸根配体的二价配位聚合物结构的影响
7. Coordination-Driven Self-Assembly of Macrocycles and 1D or 2D Coordination Polymers Using Heteroditopic Pyridyl-Carboxylate Ligands: The Case Study of 5(E)2-(3-Pyridyl)-1-Diazenyl-2-Hydroxybenzoate in Combination with {RnSn} (n = 2 and 3) [O] . -1

机译：使用异分开素吡啶基 - 羧酸盐配体的宏γ和1d或2d配位聚合物的协调自组装：壳体研究5 （e）2-（3-吡啶基）-1-二亚苯基 -2-羟基苯甲酸盐与{ RNSN}（n = 2和3）
8. Solid State Solution Behavior of Triorganotin (IV) Derivatives Containing the2,4,6-Tris-(Triflu oromethyl)Benzene 1,4-Bis(Perfluoroisopropoxy) Tetrafluorobenzene Ligands: Crystal Molecular Structures of 2,4,6-(CF3)3C6H2Sn(C6H5)3 and 1,4-(CH3)SnOC(CF)32C6F [R] . Vij, A., Kirchmeier, R. L., Willett, R. D., 1994

机译：含有2,4,6-三 - （三氟甲基）苯1,4-双（全氟异丙氧基）四氟苯配体的三有机锡（Ⅳ）衍生物的固态溶液行为：2,4,6-（CF3）3C6H2sn的晶体分子结构（ C 6 H 5）3和1,4-（CH 3）snOC（CF）32C6F

Multicomponent assembly of macrocycles and polymers by coordination of pyridyl ligands to 1,4-bis(benzodioxaborole)benzene

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