A new mode of activation of CO _2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature

Vogt M.; Gargir M.; Iron M.A.; Diskin-Posner Y.; Ben-David Y.; Milstein D.

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A new mode of activation of CO _2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature

机译：金属配体与环境温度下可逆的C-C和M-O键形成共同激活CO _2的新模式

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Team work: Although CO _2 binding to metal centers usually involves π coordination to a C?￡O group or ? bonds to the carbon or oxygen atom of the CO _2 molecule, a new mode of metal-ligand cooperative activation of CO _2 to a ruthenium PNP pincer complex involving aromatization/dearomatization steps is presented in experimental and theoretical studies (see scheme).

机译：团队合作：尽管CO _2与金属中心的键合通常涉及与C ￡ O基团或？结合到CO _2分子的碳或氧原子上，在实验和理论研究中（见方案）提出了一种新的金属配体将CO _2协同活化为钌PNP钳形复合物的方法，涉及芳香化/脱芳香化步骤。

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《Chemistry: A European journal》 |2012年第30期|共4页
作者
Vogt M.; Gargir M.; Iron M.A.; Diskin-Posner Y.; Ben-David Y.; Milstein D.;
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正文语种 eng
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CO _2 activation; density functional calculations; isotopic labeling; metal-ligand cooperation; NMR spectroscopy; PNP pincer ligands; ruthenium;

机译：CO _2活化;密度泛函计算;同位素标记;金属-配体配合;NMR光谱;PNP钳形配体;钌;

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1. A new mode of activation of CO _2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature [J] . Vogt M., Gargir M., Iron M.A., Chemistry: A European journal . 2012,第30期

机译：金属配体与环境温度下可逆的C-C和M-O键形成共同激活CO _2的新模式
2. Template Catalysis by Metal-Ligand Cooperation. C-C Bond Formation via Conjugate Addition of Non-activated Nitriles under Mild, Base-free Conditions Catalyzed by a Manganese Pincer Complex [J] . Alexander Nerush, Matthias Vogt, Urs Gellrich, Journal of the American Chemical Society . 2016,第22期

机译：金属配体合作的模板催化。锰钳配合物在温和无碱条件下通过共轭添加未活化的腈形成C-C键
3. Synthesis and reactivity of an iridium(I) acetonyl PNP complex. Experimental and computational study of metal-ligand cooperation in H-H and C-H bond activation via reversible ligand dearomatization [J] . Schwartsburd L., Iron M.A., Konstantinovski L., Organometallics . 2010,第17期

机译：铱（I）丙酮酰基PNP配合物的合成和反应性。通过可逆配体脱芳构作用激活H-H和C-H键的金属-配体配合的实验和计算研究
4. Nickel-Catalyzed Reversible C-C Bond Formation and Cleavage Reaction via Nickellacycles [C] . Masahiko Mori, Sawako Seki, Masanari Kimura Symposium on Organometallic Chemistry . 2006

机译：镍催化的可逆C-C键形成和通过尼数的切割反应
5. C-H bond activation and C-C bond formation at adjacent metals. [D] . Torkelson, Jeffrey Robert. 1998

机译：在相邻金属处的C-H键活化和C-C键形成。
6. Graphene-catalyzed formation of C≡N bonds via cleavage of C-C and N-O bonds in ethanol and nitrate under room temperature [O] . Ding Xiao, Wucong Wang, Yanzhe Gai, -1

机译：石墨烯在室温下通过乙醇和硝酸盐中C-C和N-O键的裂解形成C≡N键
7. Reversible Sigma C-C Bond Formation Between Phenanthroline Ligands Activated by (C5Me5)2Yb [O] . Nocton, Grégory,, Lukens, Wayne,, Booth, Corwin,, 2014

机译：（C5Me5）2Yb活化的菲咯啉配体之间的可逆Sigma C-C键形成

A new mode of activation of CO _2 by metal-ligand cooperation with reversible C-C and M-O bond formation at ambient temperature

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