Ortho-Quinone methides in natural product synthesis

Willis N.J.; Bray C.D.

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Ortho-Quinone methides in natural product synthesis

机译：天然产物合成中的邻醌甲基化物

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ortho-Quinone methides (o-QMs) are emerging as highly useful intermediates, the inherent reactivity of which can be used in linchpin reactions for the construction of complex natural products. This review encompasses the major contributions in this field, exemplifying the major strategies and reactivity modes which can be applied. Orchestrating reactions: ortho-Quinone methides (o-QMs) are highly labile, often transient species, the inherent reactivity of which can be used for orchestrating linchpin reactions in total synthesis. A review of their use in natural product syntheses is presented.

机译：邻醌奎宁（o-QMs）作为高度有用的中间体正在出现，其固有的反应活性可用于构建复杂天然产物的关键反应中。这篇综述涵盖了该领域的主要贡献，举例说明了可以应用的主要策略和反应模式。编排反应：邻醌奎宁（o-QMs）是不稳定的，通常是短暂的，其固有的反应活性可用于编排总合成中的关键反应。本文介绍了它们在天然产物合成中的用途。

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《Chemistry: A European journal》 |2012年第30期|共14页
作者
Willis N.J.; Bray C.D.;
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正文语种 eng
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benzopyran; cycloaddition; electrocyclic reactions; natural products; ortho-quinone methide;

机译：苯并吡喃;环加成;电环反应;天然产物;邻醌甲基化物;

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专利

1. Stereoselective Reactions of ortho-Quinone Methide and ortho-Quinone Methide Imines and Their Utility in Natural Product Synthesis [J] . Christian D.-T. Nielsen, Hossay Abas, Alan C. Spivey Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2018,第20期

机译：邻醌甲基氨基和邻醌甲基亚胺及其在天然产物合成中的效用的立体选择性反应
2. Increasing Structural Diversity of Natural Products by Michael Addition with ortho-Quinone Methide as the Acceptor [J] . Liao Ge, Fan Jie, Ludwig-Radtke Lena, The Journal of Organic Chemistry . 2020,第2期

机译：用麦克尔加入与邻醌次氨基作为受体增加天然产品的结构多样性
3. ortho-Quinone Methide Cyclizations Inspired by the Busseihydroquinone Family of Natural Products [J] . Burchill Laura, Pepper Henry P., Sumby Christopher J., Organic letters . 2019,第20期

机译：Ortho-quinone meThide yearipations，由Busseihydroquinone天然产品系列启发
4. DESIGN AND SYNTHESIS OF 12-AZA-EPOTHILONES (AZATHILONES) - NON-NATURAL NATURAL PRODUCTS WITH POTENT ANTICANCER ACTIVITY(Abstracts) [C] . Fabian Feyen, Jurg Gertsch, Markus Wartmann European Symposium on Organic Chemistry . 2007

机译：12-AZA-EPOTHILONES（Azathilones）的设计与合成 - 具有强大抗癌活动的非天然天然产品（摘要）
5. Simultaneous synthesis of both rings of chromenes via a benzannulation/ortho-quinone methide formation/electrocyclization cascade and an approach towards the asymmetric synthesis of chromenes [D] . Majumdar, Nilanjana 2012

机译：通过苯环化/邻醌甲基化物形成/电环化级联同时合成二甲基苯酮的环和不对称合成二苯甲基苯的方法
6. Applications of ortho-Quinone Methide Intermediates in Catalysis and Asymmetric Synthesis [O] . Tejas P. Pathak, Matthew S. Sigman -1

机译：邻醌甲基化物中间体的催化和不对称合成应用
7. ortho-Quinone Methide Cyclizations Inspired by the Busseihydroquinone Family of Natural Products [O] . -1

机译：Ortho-quinone meThide yearipations，由Busseihydroquinone天然产品系列启发

Ortho-Quinone methides in natural product synthesis

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