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首页> 外文期刊>Chemistry: A European journal >Endohedral metallofullerenes-filled fullerene derivatives towards multifunctional reaction center mimics
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Endohedral metallofullerenes-filled fullerene derivatives towards multifunctional reaction center mimics

机译：内嵌金属富勒烯的富勒烯衍生物对多功能反应中心的模拟

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摘要

In recent years, endohedral metallofullerenes have attracted tremendous interest not only in physics and chemistry, but also in interdisciplinary areas, such as materials and biological sciences. In this concept article we highlight recent results on different endohedral metallofullerenes based on lanthanides and their derivatives. The chemical and excited state reactivities of endohedral metallofullerenes are discussed for various endohedral clusters. Most important is the part that covers spectroscopic and kinetic assays of reductive and oxidative charge transfer evolving from photoexcited electron donors and electron acceptors, respectively, in a variety of electron donor-acceptor conjugates. Towards this end, we refer to the applications of endohedral metallofullerenes in photovoltaic devices that feature greater efficiency than devices fabricated with empty fullerenes. Herein, we focus mainly on results obtained in the groups of Akasaka, Echegoyen, and Guldi.
机译：近年来，内面金属富勒烯不仅在物理和化学领域，而且在跨学科领域（例如材料和生物科学）都引起了极大的兴趣。在此概念文章中，我们重点介绍了基于镧系元素及其衍生物的不同内表面金属富勒烯的最新研究结果。讨论了内面金属簇的内面金属富勒烯的化学和激发态反应性。最重要的是该部分涵盖了在各种电子供体-受体结合物中，分别由光激发电子供体和电子受体演变而来的还原和氧化电荷转移的光谱和动力学测定。为此，我们指的是内面金属富勒烯在光伏器件中的应用，该器件的效率要高于用空富勒烯制造的器件。在这里，我们主要集中在赤坂，Echegoyen和Guldi组中获得的结果。

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