Microwave-accelerated Ru-catalyzed hydrovinylation of alkynes and enynes: A straightforward approach toward 1,3-dienes and 1,3,5-trienes

Schabel T.; Plietker B.

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Microwave-accelerated Ru-catalyzed hydrovinylation of alkynes and enynes: A straightforward approach toward 1,3-dienes and 1,3,5-trienes

机译：微波加速Ru催化的炔烃和烯炔烃的氢化乙烯基化：一种直接的方法来制备1,3-二烯和1,3,5-三烯

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Quick, but not dirty! Microwave heating was found to have a significant effect on the Ru-catalyzed hydrovinylations of alkynes. A broad range of different terminal alkynes were coupled to methyl acrylate within just 30min in good to excellent yields (see scheme). This new protocol was transferred to the hydrovinylation of enynes as novel coupling partners in C-H-activation chemistry giving different 1,3,5-trienes as the sole products.

机译：快速，但不脏！发现微波加热对Ru催化的炔烃的氢化乙烯基化有显着影响。在短短30分钟内即可将各种不同的末端炔烃与丙烯酸甲酯偶联，获得良好至优异的收率（参见方案）。该新方案已转移至烯炔的氢乙烯基化反应中，作为C-H活化化学中的新型偶联伙伴，从而产生了不同的1,3,5-三烯作为唯一产品。

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《Chemistry: A European journal》 |2013年第22期|共4页
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Schabel T.; Plietker B.;
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catalysis; coupling; diene; microwave; ruthenium;

机译：催化偶联二烯微波钌;

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1. Microwave-accelerated Ru-catalyzed hydrovinylation of alkynes and enynes: A straightforward approach toward 1,3-dienes and 1,3,5-trienes [J] . Schabel T., Plietker B. Chemistry: A European journal . 2013,第22期

机译：微波加速Ru催化的炔烃和烯炔烃的氢化乙烯基化：一种直接的方法来制备1,3-二烯和1,3,5-三烯
2. Aqueous Wittig reactions of semi-stabilized ylides. A straightforward synthesis of 1,3-dienes and 1,3,5-trienes [J] . James McNulty, Priyabrata Das Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第41期

机译：半稳定烷基化物的水维蒂希反应。 1,3-二烯和1,3,5-三烯的直接合成
3. Aqueous Wittig reactions of semi-stabilized ylides. A straightforward synthesis of 1,3-dienes and 1,3,5-trienes [J] . James McNulty, Priyabrata Das Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2009,第41期

机译：半稳定烷基化物的水维蒂希反应。 1,3-二烯和1,3,5-三烯的直接合成
4. Ru(0)-Catalyzed Direct Synthesis of Conjugated Trienes and Tetraenes by Coupling of Conjugated Dienes with Internal Alkynes [C] . Sayori Kiyota, Seonyoung In, Nobuyuki Komine 日本化学会春季年会講演予稿集 . 2018

机译：Ru（0） - 通过用内部炔烃偶联结合共轭二烯的催化性三联和四烯的直接合成
5. Discovery and development of 3,3,3-trichloropropyl-1-triphenylphosphonium chloride: A reagent for synthesis of Z-1,3-enynes, Z,Z-1-chloro-1,3-dienes and 1,3-diynes [D] . Karatholuvhu, Maheswaran S. 2006

机译：3,3,3-三氯丙基-1-三苯基氯化chloride的发现与开发：用于合成Z-1,3-烯，Z，Z-1-氯-1,3-二烯和1,3-二炔的试剂
6. Chemoselective Reductive Cross-Coupling of 15-Diene-3-ols with Alkynes: A Facile Entry to Stereodefined Skipped Trienes [O] . Peter S. Diez, Glenn C. Micalizio -1

机译：15-二烯-3-醇的化学选择性还原的交叉耦合与炔：一个浅显的进入到stereodefined跳过三烯
7. Thioether-functionalized trifluoromethyl-alkynes, 1,3-dienes and allenes: divergent synthesis from reaction of 2-trifluoromethyl-1,3-conjugated enynes with sulfur nucleophiles [O] . Huayu Cheng, Xiaofan Zhou, Anjing Hu, 2018

机译：硫醚官能化三氟甲基 - 炔，1,3-二烯和艾叶：与硫亲核试剂的2-三氟甲基-1,3-缀合的兴奋反应发散

Microwave-accelerated Ru-catalyzed hydrovinylation of alkynes and enynes: A straightforward approach toward 1,3-dienes and 1,3,5-trienes

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