Gold/Acid-Co-catalyzed Direct Microwave-Assisted Synthesis of Fused Azaheterocycles from Propargylic Hydroperoxides

Benito Alcaide; Pedro Almendros; M. Teresa Quirós

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Gold/Acid-Co-catalyzed Direct Microwave-Assisted Synthesis of Fused Azaheterocycles from Propargylic Hydroperoxides

机译：金/酸共催化直接微波辅助从炔丙基氢过氧化物合成熔融氮杂杂环。

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摘要

The gold–acid-co-catalyzed synthesis of nine series of fused azaheterocycles with structural diversity starting from the same synthons as readily available propargylic hydroperoxides and aromatic amines has been achieved. The overall tandem process consists in a gold-catalyzed hydroperoxide rearrangement/Michael reaction followed by a final acid-catalyzed cyclization.

机译：金-酸共催化合成了九个系列的具有结构多样性的稠合氮杂杂环，它们由与容易获得的炔丙基氢过氧化物和芳族胺相同的合成子开始。整个串联过程包括金催化的氢过氧化物重排/ Michael反应，然后进行最终的酸催化的环化反应。

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《Chemistry: A European journal》 |2014年第12期|共10页
作者
Benito Alcaide; Pedro Almendros; M. Teresa Quirós;
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正文语种 eng
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alkynes; amines; gold; heterocycles; peroxides;

机译：炔烃;胺;金;杂环;过氧化物;

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专利

1. Gold/Acid-Co-catalyzed Direct Microwave-Assisted Synthesis of Fused Azaheterocycles from Propargylic Hydroperoxides [J] . Benito Alcaide, Pedro Almendros, M. Teresa Quirós Chemistry: A European journal . 2014,第12期

机译：金/酸共催化直接微波辅助从炔丙基氢过氧化物合成熔融氮杂杂环。
2. Thiosalicylic Acid Catalyzed Multicomponent Reactions: Microwave-Assisted Synthesis of New Extended Angular Fused Azaheterocycles [J] . Ge Zhang, Ning Ma, Bo Jiang, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2010,第23期

机译：硫代水杨酸催化的多组分反应：微波辅助合成的新的扩展角熔融氮杂杂环化合物。
3. Thiosalicylic Acid Catalyzed Multicomponent Reactions: Microwave-Assisted Synthesis of New Extended Angular Fused Azaheterocycles [J] . Ge Zhang, Ning Ma, Bo Jiang, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2010,第23期

机译：硫磺酸催化的多组分反应：微波辅助合成新的延长角度融合的azeahetercycly
4. Ruthenium- and Gold-Catalyzed Tandem Reaction: Synthesis of Substituted Oxazoles from Propargylic Alcohols and Amides [C] . Marilyn Daisy Milton, Youichi Inada, Yoshiaki Nishibayashi, Symposium on Organometallic Chemistry . 2004

机译：钌和金催化串联反应：从丙基醇和酰胺的合成取代的恶唑
5. Part I. One-pot synthesis of secondary alcohols and one-pot asymmetric synthesis of secondary propargylic alcohols. Part II. Redox isomerization of secondary propargylic alcohols to enones. Part III. Synthesis study towards C9-C14 fragment of (+)-discodermolide. Part IV. Asymmetric synthesis of anti, anti-stereotriad building blocks for polypropionate natural products [D] . Xie, Qiuzhe 2007

机译：第一部分：仲醇的一锅法合成和仲炔丙醇的一锅法不对称合成。第二部分仲炔丙醇的氧化还原异构化为烯酮。第三部分（+）-discodermolide C9-C14片段的合成研究。第四部分聚丙烯酸酯天然产物的抗，抗立体三环构建基的不对称合成
6. Direct Synthesis of Azaheterocycles from N-Aryl/Vinyl Amides. Synthesis of 4-(Methylthio)-2-phenylquinazoline and 4-(4-Methoxyphenyl)-2-phenylquinoline [O] . Omar K. Ahmad, Jonathan William Medley, Alexis Coste, -1

机译：从N-芳基/乙烯基酰胺氮杂杂环的直接合成。合成4-（甲硫基）-2-苯基和4-（4-甲氧基苯基）-2-苯基喹啉
7. Synthesis of Brominated Directly Fused Diporphyrins through Gold(III)-Mediated Oxidation [O] . -1

机译：通过金（III）介导的氧化溴化直接熔化的偶卟啉的合成

Gold/Acid-Co-catalyzed Direct Microwave-Assisted Synthesis of Fused Azaheterocycles from Propargylic Hydroperoxides

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