Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages

Tomonori Iitsuka; Koji Hirano; Tetsuya Satoh; Masahiro Miura

首页> 外文期刊>Chemistry: A European journal >Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages

【24h】

Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages

机译：铑催化的3-苯基噻吩与涉及双C-H键断裂的炔烃的环状偶联。

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Double C-H bond activation took place efficiently upon treatment of 3-phenylthiophenes with alkynes in the presence of a rhodium catalyst and a copper salt oxidant to form the corresponding naphthothiophene derivatives. Dehydrogenative coupling with alkenes was also found to occur on the phenyl moiety rather than the thiophene ring. These reactions provide straightforward synthetic methods for p-conjugated molecules involving a thiophene unit from readily available, simple building blocks.

机译：在铑催化剂和铜盐氧化剂的存在下，用炔烃处理3-苯基噻吩可有效地进行双C-H键活化，以形成相应的萘噻吩衍生物。还发现与烯烃的脱氢偶联发生在苯基部分而不是噻吩环上。这些反应从容易获得的简单结构单元为涉及噻吩单元的p-共轭分子提供了简单的合成方法。

著录项

来源
《Chemistry: A European journal》 |2014年第2期|共5页
作者
Tomonori Iitsuka; Koji Hirano; Tetsuya Satoh; Masahiro Miura;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
activation; naphthothiophene; reactions;

机译：活化;萘噻吩;反应;

相似文献

外文文献
中文文献
专利

1. Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages [J] . Tomonori Iitsuka, Koji Hirano, Tetsuya Satoh, Chemistry: A European journal . 2014,第2期

机译：铑催化的3-苯基噻吩与涉及双C-H键断裂的炔烃的环状偶联。
2. Rhodium-Catalyzed Annulative Coupling of Isothiazoles with Alkynes through N-S Bond Cleavage [J] . Mihara Gen, Noguchi Teppei, Nishii Yuji, Organic letters . 2020,第2期

机译：通过N-S粘合裂解铑催化用alothiazoles与alithiazoles的环形偶联
3. Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C-H Bond Cleavage [J] . Yokoyama Yuki, Unoh Yuto, Bohmann Rebekka Anna, Chemistry Letters . 2015,第8期

机译：铑通过定向C-H键断裂直接催化苯甲硫酰胺与烯烃和炔烃的偶联
4. Modified Cp-Rhodium(III)-Catalyzed Coupling Reactions of Heterole-Carboxamides with Alkynes via C-H Bond Cleavage [C] . Takayuki Yamada, Yu Shibata, Ken Tanaka 日本化学会春季年会講演予稿集 . 2018

机译：通过C-H键切割 - 改性Cp-Rhodium（III） - 用炔烃与炔烃的催化反应
5. Palladium-catalyzed reductive cross-coupling reactions and the analysis of site-selectivity in rhodium-catalyzed C-H amination reactions. [D] . DeLuca, Ryan James. 2014

机译：钯催化的还原交叉偶联反应和铑催化的C-H胺化反应中的位点选择性分析。
6. C-H Bond Functionalization via Hydride Transfer: Direct Coupling of Unactivated Alkynes and sp3 C-H Bonds Catalyzed by Platinum Tetraiodide [O] . Paul A. Vadola, Dalibor Sames -1

机译：通过氢转移C-H键功能化：未激活炔烃的直接耦合和sp3 C-H键的催化作用白金四碘化物
7. Rhodium-Catalyzed Oxidative Coupling of Triarylmethanols with Internal Alkynes via Successive C-H and C-C Bond Cleavages [O] . -1

机译：通过连续的C-H和C-C键裂解铑催化三芳基甲醇的三芳基甲醇的氧化偶联
8. Redox Catalysis Involving Substrate Photooxidation with Catalyst Regeneration bySubstrate Reduction. Simultaneous Oxidative C-H Bond Cleavage and Reductive C-S Bond Cleavage in Thioethers Catalyzed by W10O324- [R] . Chambers, R. C., Hill, C. L. 1990

机译：氧化还原催化与底物光氧化反应的催化剂再生通过底物还原。 W10O324催化的硫醚同时氧化C-H键断裂和还原C-s键断裂

Rhodium-Catalyzed Annulative Coupling of 3-Phenylthiophenes with Alkynes Involving Double C-H Bond Cleavages

摘要

著录项

相似文献

相关主题

期刊订阅