Pt_3Co Concave Nanocubes: Synthesis, Formation Understanding, and Enhanced Catalytic Activity toward Hydrogenation of Styrene

Chenyu Wang; Cuikun Lin; Lihua Zhang; Zewei Quan; Kai Sun; Bo Zhao; Feng Wang; Nathan Porter; Yuxuan Wang; Jiye Fang

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Pt_3Co Concave Nanocubes: Synthesis, Formation Understanding, and Enhanced Catalytic Activity toward Hydrogenation of Styrene

机译：Pt_3Co凹形纳米立方体：合成，形成理解和增强的氢化苯乙烯催化活性。

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We report a facile synthesis route to prepare highquality Pt_3Co nanocubes with a concave structure, and further demonstrate that these concave Pt_3Co nanocubes are terminated with high-index crystal facets. The success of this preparation is highly dependent on an appropriate nucleation process with a successively anisotropic overgrowth and a preservation of the resultant high-index planes by control binding of oleyl-amine/oleic acid with a fine-tuned composition. Using a hydrogenation of styrene as a model reaction, these Pt_3Co concave nanocubes as a new class of nanocatalysts with more open structure and active atomic sites located on their high-index crystallographic planes exhibit an enhanced catalytic activity in comparison with low-indexed surface terminated Pt_3Co nanocubes in similar size.

机译：我们报告了一种容易的合成路线，以制备具有凹形结构的高质量Pt_3Co纳米立方体，并进一步证明这些凹形Pt_3Co纳米立方体以高折射率晶面终止。该制备方法的成功高度依赖于适当的成核过程，该过程具有连续的各向异性过度生长，以及通过控制油酸胺/油酸与微调的组合物的结合来保持所得的高折射率平面。使用苯乙烯氢化作为模型反应，这些Pt_3Co凹形纳米立方作为新型纳米催化剂，其低指数表面终止的Pt_3Co与具有更高开放结构和位于高指数晶体平面上的活性原子位点相比，具有增强的催化活性。大小相似的纳米立方体。

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《Chemistry: A European journal》 |2014年第6期|共7页
作者
Chenyu Wang; Cuikun Lin; Lihua Zhang; Zewei Quan; Kai Sun; Bo Zhao; Feng Wang; Nathan Porter; Yuxuan Wang; Jiye Fang;
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正文语种 eng
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synthesis; formation; report;

机译：综合;形成;报告;

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1. Pt_3Co Concave Nanocubes: Synthesis, Formation Understanding, and Enhanced Catalytic Activity toward Hydrogenation of Styrene [J] . Chenyu Wang, Cuikun Lin, Lihua Zhang, Chemistry: A European journal . 2014,第6期

机译：Pt_3Co凹形纳米立方体：合成，形成理解和增强的氢化苯乙烯催化活性。
2. Urea hydrogen bond donor-mediated synthesis of high-index faceted platinum concave nanocubes grown on multi-walled carbon nanotubes and their enhanced electrocatalytic activity [J] . Wei Lu, Liu Kai, Mao Yu-Jie, Physical chemistry chemical physics: PCCP . 2017,第47期

机译：尿素氢键供体介导的高折射率刻录铂凹纳米型在多壁碳纳米管上生长的合成及其增强的电催化活性
3. Chemical etching of graphene-supported PdPt alloy nanocubes into concave nanostructures for enhanced catalytic hydrogen production from alkaline formaldehyde aqueous solution [J] . Zaixiang Xu, Yuzhen Zhu, Lijie Bai Inorganic Chemistry Frontiers . 2017,第10期

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4. Catalytic activity of carbon nanotubes and other carbon materials for oxidative dehydrogenation of ethylbenzene to styrene [C] . N. Maksimova, G. Mestl, R. Schloegl 3rd International Symposium on Reaction Kinetics and the Development and Operation of Catalytic Processes, Apr 22-25, 2001, Oostende, Belgium . 2001

机译：碳纳米管和其他碳材料对乙苯氧化脱氢制苯乙烯的催化活性
5. Part One. Synthesis of optically active tryptophan derivatives with potential activity as indoleamine 2,3-dioxygenase inhibitors: An approach via asymmetric catalytic hydrogenation. Part Two. Design, synthesis and pharmacology of selective ligands for alpha1-containing GABA(A)/benzodiazepine receptor subtypes: SAR studies of beta-carbolines at positions -3 and -6 and their corresponding bivalent ligands. Part Three. First enantiospecific total synthesis of the important biogenetic intermediates, (+)-polyneuridine and (+)-polyneuridine aldehyde, as well as 16-epi-vellosimine and macusine A. [D] . Yin, Wenyuan. 2007

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机译：大规模合成具有高刻面的钯凹面纳米立方体以持续提高催化性能
7. Pt 3 Co Concave Nanocubes: Synthesis, Formation Understanding, and Enhanced Catalytic Activity toward Hydrogenation of Styrene [O] . Wang Chenyu, Lin Cuikun, Zhang Lihua, 2014

机译：pt 3 Co凹面纳米立方体：合成，形成理解和增强的苯乙烯加氢催化活性

Pt_3Co Concave Nanocubes: Synthesis, Formation Understanding, and Enhanced Catalytic Activity toward Hydrogenation of Styrene

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