Di- and Trinuclear Gold Complexes of Diphenylphosphinoethyl-Functionalised Imidazolium Salts and their N-Heterocyclic Carbenes: Synthesis and Photophysical Properties

Bestgen Sebastian; Gamer Michael T.; Lebedkin Sergei; Kappes Manfred M.; Roesky Peter W.

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Di- and Trinuclear Gold Complexes of Diphenylphosphinoethyl-Functionalised Imidazolium Salts and their N-Heterocyclic Carbenes: Synthesis and Photophysical Properties

机译：二苯基膦乙基功能化的咪唑鎓盐及其N杂环卡宾的双核和三核金配合物：合成和光物理性质

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Diphenylphosphinoethyl-functionalised imidazolium salts and their silver-carbene complexes were used to synthesise a series of di- and trinuclear gold complexes through ligand exchange and transmetallation, respectively. Besides a few positively charged macrocyclic compounds with different anions (both with and without activation of the carbene function), we were able to obtain neutral polynuclear complexes by varying the gold precursor. The synthesised gold complexes show a variety of photophysical properties, including bright white photoluminescence at ambient temperature.

机译：二苯基膦乙基官能化的咪唑鎓盐及其银-卡宾配合物分别用于通过配体交换和金属转移作用合成一系列二核和三核金配合物。除了一些带有不同阴离子的带正电荷的大环化合物（具有和不具有卡宾功能的活化），我们还能够通过改变金前体来获得中性多核配合物。合成的金络合物显示出多种光物理性质，包括在环境温度下的亮白色光致发光。

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《Chemistry: A European journal》 |2015年第2期|共14页
作者
Bestgen Sebastian; Gamer Michael T.; Lebedkin Sergei; Kappes Manfred M.; Roesky Peter W.;
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正文语种 eng
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aurophilicity; gold; luminescence; N-heterocyclic carbenes; phosphines;

机译：亲金性;金;发光;N-杂环卡宾;膦;

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1. Di- and Trinuclear Gold Complexes of Diphenylphosphinoethyl-Functionalised Imidazolium Salts and their N-Heterocyclic Carbenes: Synthesis and Photophysical Properties [J] . Bestgen Sebastian, Gamer Michael T., Lebedkin Sergei, Chemistry: A European journal . 2015,第2期

机译：二苯基膦乙基功能化的咪唑鎓盐及其N杂环卡宾的双核和三核金配合物：合成和光物理性质
2. Mono-, di-, and trinuclear luminescent silver(I) and gold(I) N-heterocyclic carbene complexes derived from the picolyl-substituted methylimidazolium salt: 1-methyl-3-(2-pyridinylmethyl)-1H-imidazolium tetrafluoroborate [J] . Catalano VJ, Moore AL Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第19期

机译：单，二和三核发光银（I）和金（I）由吡啶甲基取代的甲基咪唑鎓盐衍生的N-杂环卡宾配合物：1-甲基-3-（2-吡啶基甲基）-1H-咪唑四氟硼酸酯
3. Synthesis, characterization, crystal structure and antibacterial properties of N- and O-functionalized (benz)imidazolium salts and their N-heterocyclic carbene silver(I) complexes [J] . Achar Gautam, Hokrani Pallavi Prakash, Brinda K. N., Journal of Molecular Structure . 2019,第期

机译：N-和O-官能化（苯子）咪唑鎓盐及其N-杂环碳酸银（I）配合物的合成，表征，晶体结构和抗菌性质
4. Synthesis and Photophysical Properties of Four-Coordinate N-heterocyclic Carbene Copper(I) Complex Emitting Material with Brightly Luminescence [C] . Qingzhi Su, Chaoyang Chai, Feng Zhao International Conference on Energy and Environmental Protection . 2018

机译：四坐标N-杂环碳铜（I）复合物发光材料的合成与光学性质，具有明亮的发光
5. N-heterocyclic carbene catalysis: Expansion of substrate scope and synthesis of electronically diverse tetraaryl N-heterocyclic imidazolium carbene ligands [D] . Ogle, James William 2008

机译：N-杂环卡宾催化：扩大底物范围并合成电子多样性的四芳基N-杂环咪唑鎓卡宾配体
6. Synthesis, Structures, and Photophysical Properties of Novel Four-Coordinate Cu(I) Complexes Supported by Chelating N-Heterocyclic Carbene Ligands [O] . Zhiqiang Wang, Xiaojuan Sun, Chen Xu, 1970

机译：N-杂环卡宾配体支持的新型四配位Cu（I）配合物的合成，结构和光物理性质
7. Back Cover: Di- and Trinuclear Gold Complexes of Diphenylphosphinoethyl-Functionalised Imidazolium Salts and their N-Heterocyclic Carbenes: Synthesis and Photophysical Properties (Chem. Eur. J. 2/2015) [O] . Sebastian Bestgen, Michael T. Gamer, Sergei Lebedkin, 2015

机译：封底：二苯基膦酰基官能化咪唑鎓盐及其正杂环甲苯的二核金复合物：合成和光药性（Chem.EUR。J.2 / 2015）

Di- and Trinuclear Gold Complexes of Diphenylphosphinoethyl-Functionalised Imidazolium Salts and their N-Heterocyclic Carbenes: Synthesis and Photophysical Properties

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