Dual Gold-Catalyzed Head-to-Tail Coupling of Iodoalkynes

Mader Steffen; Molinari Lise; Rudolph Matthias; Rominger Frank; Hashmi A. Stephen K.

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Dual Gold-Catalyzed Head-to-Tail Coupling of Iodoalkynes

机译：碘炔的双金催化头尾耦合

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摘要

Various haloalkynes are converted in the presence of a dual activation gold catalyst. Via a dual activation process a completely atom economic head-to-tail coupling delivers gem-dihalogenated conjugated enynes as valuable building blocks for organic synthesis.

机译：在双活化金催化剂的存在下，各种卤代炔烃被转化。通过双重激活过程，完全原子经济的头尾耦合可将宝石-二卤代共轭烯炔作为有机合成的重要组成部分。

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《Chemistry: A European journal》 |2015年第10期|共4页
作者
Mader Steffen; Molinari Lise; Rudolph Matthias; Rominger Frank; Hashmi A. Stephen K.;
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正文语种 eng
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alkenes; alkynes; dual activation; gold; halogenated compounds;

机译：烯烃;炔烃;双重活化;金;卤代化合物;

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1. Dual Gold-Catalyzed Head-to-Tail Coupling of Iodoalkynes [J] . Mader Steffen, Molinari Lise, Rudolph Matthias, Chemistry: A European journal . 2015,第10期

机译：碘炔的双金催化头尾耦合
2. Copper-catalyzed cross-coupling of 1-iodoalkynes with organostannanes [J] . Kang SK., Jiao XG., Kim WY. Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 1998,第9期

机译：铜催化的1-碘炔与有机锡的交叉偶联
3. SMI2-MEDIATED COUPLING REACTIONS BETWEEN IODOALKYNES AND KETONES OR ALDEHYDES TO GIVE PROPARGYL ALCOHOLS [J] . Kunishima M., Kono K., Hioki K., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第21期

机译：碘代烷基与酮或醛之间的SMI2介导的偶联反应产生丙基丙烯醇
4. Decoupling Control Method of Asymmetric Dual Three-Phase PMSM with Mutual Coupling Inductance [C] . Gyu Cheol Lim, Jonghun Choi, Gwangyol Noh, IEEE Applied Power Electronics Conference and Exposition . 2021

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5. Duality and Axion Couplings in Two-Dimensional Supersymmetric Quantum Field Theories [D] . Gon?alves Caldeira, Jo?o Manuel. 2018

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6. Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes [O] . Manuel Hofer, Teresa de Haro, Enrique Gómez-Bengoa, 2019

机译：芳烃和炔烃的金催化氧化偶联中的氧化剂形态和阴离子配体效应
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Dual Gold-Catalyzed Head-to-Tail Coupling of Iodoalkynes

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