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Graphene on Si(111)7×7

机译:Si(111)7×7上的石墨烯

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We demonstrate that it is possible to mechanically exfoliate graphene under ultrahigh vacuum conditions on the atomically well defined surface of single crystalline silicon. The flakes are several hundred nanometers in lateral size and their optical contrast is very faint, in agreement with calculated data. Single-layer graphene is investigated by Raman mapping. The graphene and 2D peaks are shifted and narrowed compared to undoped graphene. With spatially resolved Kelvin probe measurements we show that this is due to p-type doping with hole densities of n _h6×10 ~(12)cm ~2. The in vacuo preparation technique presented here should open up new possibilities to influence the properties of graphene by introducing adsorbates in a controlled way.
机译:我们证明有可能在超高真空条件下在单晶硅的原子清晰定义的表面上机械剥离石墨烯。薄片的横向尺寸为几百纳米,其光学对比度非常微弱,与计算得出的数据一致。通过拉曼映射研究单层石墨烯。与未掺杂的石墨烯相比,石墨烯和2D峰移动并变窄。通过空间分辨开尔文探针测量,我们证明这是由于p型掺杂所致,空穴密度为n _h6×10〜(12)cm〜2。本文介绍的真空制备技术应开辟新的可能性,即通过以受控方式引入吸附物来影响石墨烯的性能。

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