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CSJ acting as a versatile highly efficient greener resource for organic transformations

机译:CSJ成为有机转化的通用高效绿色资源

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摘要

Simple, new, greener and efficient alternatives to the existing protocols have been developed for the reduction of aromatic aldehydes to their corresponding alcohols, decarboxylation of substituted benzoic acids (C-6-C-1) and substituted cinnamic acids (C-6-C-3) with a hydroxyl group at the para position with respect to the acid group to corresponding phenolic compounds and vinyl phenols respectively by using a natural feedstock, cucumber juice (CSJ), which acts as a greener solvent system, performing a substrate-selective reaction. Additionally, the hydrolysis of the acetyl as well as the benzoyl group of aromatic compounds has been carried out to afford excellent yield by CSJ.
机译:已开发出简单,新颖,绿色和有效的替代方案,用于将芳族醛还原为相应的醇,将取代的苯甲酸(C-6-C-1)和取代的肉桂酸(C-6-C)脱羧-3)通过使用天然原料黄瓜汁(CSJ)(相对绿色的溶剂系统)对相应的酚类化合物和乙烯基酚分别在相对于酸的对位的羟基上进行底物选择性反应。另外,已经进行了芳族化合物的乙酰基和苯甲酰基的水解,以通过CSJ提供优异的产率。

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