Superposition model study of Cr3+ doped tetra methyl ammonium cadmium chloride

Kripal Ram; Yadav Awadhesh Kumar

首页> 外文期刊>Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy >Superposition model study of Cr3+ doped tetra methyl ammonium cadmium chloride

【24h】

Superposition model study of Cr3+ doped tetra methyl ammonium cadmium chloride

机译：Cr3 +掺杂的四甲基氯化铵镉的叠加模型研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The zero field splitting parameter D of Cr3+ doped in tetra methyl ammonium cadmium chloride (TMCC) is calculated with perturbation formula using microscopic spin Hamiltonian theory and crystal field parameters from superposition model. The theoretically calculated ZFS parameter for Cr3+ in TMCC single crystal is compared with the experimental value obtained by electron paramagnetic resonance (EPR). The local structure distortion is considered to obtain the crystal field parameters. The theoretical study gives the ZFS parameter D similar to that from experiment. However, calculation considering small distortion in local structure around Cr3+ gives better agreement with the experimental value of ZFS parameter. (C) 2014 Elsevier B.V. All rights reserved.

机译：利用微观自旋哈密顿理论和叠加模型的晶体场参数，利用摄动公式，计算了四甲基氯化铵镉（TMCC）中Cr3 +的零场分裂参数D。将理论计算的TMCC单晶中Cr3 +的ZFS参数与通过电子顺磁共振（EPR）获得的实验值进行比较。考虑局部结构变形以获得晶体场参数。理论研究得出的ZFS参数D与实验相似。但是，考虑到Cr3 +周围局部结构的小变形的计算与ZFS参数的实验值具有更好的一致性。（C）2014 Elsevier B.V.保留所有权利。

著录项

来源
《Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy》 |2015年第1期|共4页
作者
Kripal Ram; Yadav Awadhesh Kumar;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Inorganic compounds; Crystal fields; Optical properties; Electron paramagnetic resonance;

机译：无机化合物;晶体场;光学性质;电子顺磁共振;

相似文献

外文文献
中文文献
专利

1. Superposition model study of Cr3+ doped tetra methyl ammonium cadmium chloride [J] . Kripal Ram, Yadav Awadhesh Kumar Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2015,第Pta1期

机译：CR3 +掺杂四甲基氯化铵的叠加模型研究
2. Single crystal EPR, optical absorption and superposition model study of Cr3+ doped ammonium dihydrogen phosphate [J] . Ram Kripal, Sangita Pandey Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2010,第1期

机译：Cr3 +掺杂磷酸二氢铵的单晶EPR，光吸收和叠加模型研究
3. EPR, Optical Absorption and Superposition Model Studies of Fe~(3+) Doped Ammonium Hydrogen Succinate [J] . Ram Kripal, Shri Devi Pandey Advances in Alloys and Compounds . 2015,第1期

机译：Fe〜（3+）掺杂琥珀酸氢铵的EPR，光吸收和叠加模型研究
4. EXPERIMENTAL STUDY OF A NOVEL COLD STORAGE MEDIUM - TETRA-BUTYL AMMONIUM CHLORIDE HYDRATE [C] . YINGMING XIE, JINGJING WEI, DAOPING LIU, IIR Conference on Phase-Change Materials and Slurries for Refrigeration and Air Conditioning . 2010

机译：一种新型冷藏介质 - 四丁基氯化铵水合物的实验研究
5. The Effects of Tetra-n-Butyl Ammonium Bromide and Tetra-n-Butyl Ammonium Chloride on the Phase Equilibria, Solubility and Modelling of Propane Hydrate Formation [D] . Langlois-Rahme, Gabriel. 2019

机译：四丁基溴化铵和四正丁基氯化铵对丙烷水合物形成相平衡，溶解度和建模的影响
6. Crystal structures of tetramethylammonium (22′-bipyridine)tetracyanidoferrate(III) trihydrate and poly(22′-bipyridine-κ2NN′)di-μ2-cyanido-dicyanido(μ-ethylenediamine)(ethylenediamine-κ2NN′)cadmium(II)iron(II) monohydrate [O] . Songwuit Chanthee, Wikorn Punyain, Supawadee Namuangrak, 2016

机译：三水合四甲基铵盐（22-联吡啶）四氰基高铁酸盐（III）和聚（（22-联吡啶-κ2）NN）二-μ2-氰基-二氰基（μ-乙基二烯胺）（乙基二胺-κ2NN）镉（II）铁（II）一水合物
7. XII.—Studies on the Pharmacological Action of Tetra-Alkyl-Ammonium Compounds: II. The Action of Tetra-Ethyl-Ammonium Chloride [O] . C. R. Marshall 1915

机译：XII。 - 研究四烷基 - 铵化合物的药理作用：II。四乙基 - 氯化铵的作用
8. Health Advisories for 25 Organics (Including Acrylamide, Benzene, Carbon Tetrachloride, Chlorobenzene, Dichlorobenzene(s), 1,2-Dichloroethane, 1,1-Dichloroethylene, Cis-1,2-Dichloroethylene, Trans-1,2-Dichloroethylene, Dichloromethane, P-Dioxane, Dioxin, Epichlorohydrin, Ethylbeneze, Ethylene Glycol, Hexachlorobenezene, Hexane, Methyl Ethyl Ketone, Styrene, Tetrachloroethylene, Toluene, 1,1,1-Trichloroethane, Trichloroethylene, Vinyl Chloride, Xylenes) (RE-ANNOUNCEMENT of PB87-206306 - see notes field for explanation) [R] . 1987

机译：25种有机物的健康咨询（包括丙烯酰胺，苯，四氯化碳，氯苯，二氯苯，1,2-二氯乙烷，1,1-二氯乙烯，顺-1,2-二氯乙烯，反式-1,2-二氯乙烯，二氯甲烷），对二恶烷，二恶英，环氧氯丙烷，乙基苯乙烯，乙二醇，六氯苯，己烷，甲基乙基酮，苯乙烯，四氯乙烯，甲苯，1,1,1-三氯乙烷，三氯乙烯，氯乙烯，二甲苯）（pB87-的重新公告） 206306 - 请参阅备注字段以获取解释）

Superposition model study of Cr3+ doped tetra methyl ammonium cadmium chloride

摘要

著录项

相似文献

相关主题

期刊订阅