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X-ray diffraction study of the structural phase transition in MnAs under high magnetic fields

机译:强磁场下MnAs中结构相变的X射线衍射研究

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The structural phase transition induced by magnetic fields on MnAs was observed by the X-ray diffraction measurements in high magnetic fields up to 4 T. Magnetization measurements showed that Curie temperature T-C was 315.5 K for increasing temperatures and a metamagnetic transition from the paramagnetic to the ferromagnetic state occurred above T-C. The structural transformation from the hexagonal NiAs-type to the orthorhombic MnP-type structure was confirmed at T-C with increasing temperature from 290 to 319 K via two-phase coexistence region. The X-ray diffraction profiles at 319 K showed the single phase of the MnP-type structure in zero field and applying magnetic field of 3 T caused appearance of the Brag peak of the hexagonal structure. On further increase of magnetic fields, the single phase of the hexagonal structure was observed above 3.5 T in the forced ferromagnetic state. Both the magnetic and structural transitions induced by magnetic fields above T-C were first order with a hysteresis and had a close relationship between each other. (C) 2004 Elsevier B.V. All rights reserved.
机译:在高达4 T的高磁场中,通过X射线衍射测量观察到了MnAs上的磁场引起的结构相变。磁化测量显示,居里温度TC为315.5 K(随温度升高),并且从顺磁向顺磁转变。铁磁状态发生在TC以上。随着温度从290 K升高到319 K,通过两相共存区域,在T-C处证实了从六方NiAs型向正交MnP型结构的结构转变。 319 K的X射线衍射图表明MnP型结构的单相处于零场,施加3 T磁场导致出现六方结构的Brag峰。随着磁场的进一步增加,在强制铁磁状态下,六角形结构的单相在3.5 T以上被观察到。由高于T-C的磁场引起的磁跃迁和结构跃迁都是一阶的,具有磁滞现象,并且彼此之间具有密切的关系。 (C)2004 Elsevier B.V.保留所有权利。

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