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Annealing temperature effect on the structural, optical and electrical properties of ZnS thin films

机译:退火温度对ZnS薄膜结构,光学和电学性质的影响

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Zinc sulfide thin films were prepared on glass substrates at room temperature using a chemical bath deposition method. The obtained films were annealed at temperatures ranging from 100 to 500 °C in steps of 100 °C for 1 h. The films were characterized by X-ray diffraction (XRD), Raman spectroscopy, energy dispersive X-ray analysis (EDX), optical absorption spectra, and electrical measurements. X-ray diffraction analysis indicates that the deposited films have an amorphous structure, but after being annealed at 500 °C, they change to slightly polycrystalline. The optical constants such as the refractive index (n_r), the extinction coefficient (k), and the real (ε_1) and imaginary (ε_2) parts of the dielectric constant are calculated depending on the annealing temperature. Aside from the ohmic characteristics of the IV curve, a nonlinear IV curve owing to the Schottky contact is also found, and the barrier heights (φ_(bn)) for Au-ZnS and In-ZnS heterojunctions are calculated. The conductivity type was identified by the hot-probe technique.
机译:使用化学浴沉积法在室温下在玻璃基板上制备硫化锌薄膜。将获得的薄膜在100到500摄氏度的温度范围内以100摄氏度的步幅退火1小时。通过X射线衍射(XRD),拉曼光谱,能量色散X射线分析(EDX),光学吸收光谱和电学测量来表征薄膜。 X射线衍射分析表明,沉积的膜具有非晶结构,但是在500℃下退火后,它们变为微多晶。根据退火温度计算出光学常数,例如折射率(n_r),消光系数(k)以及介电常数的实部(ε_1)和虚部(ε_2)。除了IV曲线的欧姆特性外,还发现了由于肖特基接触引起的非线性IV曲线,并计算了Au / n-ZnS和In / n-ZnS异质结的势垒高度(φ_(bn))。通过热探针技术识别导电类型。

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