Multi-scale scanning tunneling microscopy imaging of self-organized regioregular poly(3-hexylthiophene)films

B.Grevin; P.Rannou; R.Payerne; J.P.Travers

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Multi-scale scanning tunneling microscopy imaging of self-organized regioregular poly(3-hexylthiophene)films

机译：自组织区域规则聚（3-己基噻吩）薄膜的多尺度扫描隧道显微镜成像

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Two-dimensional self-organized poly(3-hexylthiophene) films on highly oriented pyrolytic graphite have been probed at the soldi/substrate interface by scanning tunneling microscopy (STM). Structural morphology and typical polymer conformations are visualized and discussed from mesoscopic to nanoscopic scales,including mesoscopic assembly of polycrystals,crystalline monodomain orientations and sizes,grain boundaries,chain folds,and other conformational features. STM estimation of teh average chain length is in remarkably good agreement with that deriv4ed from size-exclusion chromatography. The multiscale analysis supports a picture where heterogeneities exist at different length scales.

机译：通过扫描隧道显微镜（STM），已在soldi /基质界面上探测了高取向热解石墨上的二维自组织聚（3-己基噻吩）薄膜。可视化并讨论了从中观到纳米尺度的结构形态和典型的聚合物构象，包括多晶的介观组装，晶体单畴取向和大小，晶界，链折叠以及其他构象特征。 STM估算的平均链长与尺寸排阻色谱法的估算值非常吻合。多尺度分析支持一张图片，其中异质性以不同的长度尺度存在。

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《The Journal of Chemical Physics》 |2003年第15期|共6页
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B.Grevin; P.Rannou; R.Payerne; J.P.Travers;
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1. Multi-scale scanning tunneling microscopy imaging of self-organized regioregular poly(3-hexylthiophene)films [J] . B.Grevin, P.Rannou, R.Payerne, The Journal of Chemical Physics . 2003,第15期

机译：自组织区域规则聚（3-己基噻吩）薄膜的多尺度扫描隧道显微镜成像
2. Molecular Weight Dependence of Chain Packing and Semicrystalline Structure in Oriented Films of Regioregular Poly(3-hexylthiophene) Revealed by High-Resolution Transmission Electron Microscopy [J] . Brinkmann M, Rannou P Macromolecules . 2009,第4期

机译：高分辨率透射电子显微镜揭示的区域规则聚（3-己基噻吩）取向膜中链堆积和半结晶结构的分子量依赖性
3. Multiscale Scanning Tunneling Microscopy Study of Self-Assembly Phenomena in Two-Dimensional Polycrystals of π-Conjugated Polymers: The Case of Regioregular Poly(dioctylbithiophene-alt-fluore-none) [J] . Michael Brun, Renaud Demadrille, Patrice Rannou, Advanced Materials . 2004,第23a24期

机译：π共轭聚合物二维多晶体自组装现象的多尺度扫描隧道显微镜研究：区域规则聚（二辛基联噻吩-alt-荧光-无）的情况
4. Synthesis, mobility, and conductivity of well-defined regioregular poly(3-hexylthiophene) and diblock copolymers of regioregular poly(3-hexylthiophene) [C] . Genevieve Sauve, Rui Zhang, Shijun Jia, Organic Field-Effect Transistors V . 2006

机译：定义明确的区域规则的聚（3-己基噻吩）和区域规则的聚（3-己基噻吩）的二嵌段共聚物的合成，迁移率和电导率
5. Scanning probe analysis of polydiacetylene nanowires and poly(3-hexylthiophene) thin films. [D] . Giridharagopal, Rajiv. 2010

机译：聚二乙炔纳米线和聚（3-己基噻吩）薄膜的扫描探针分析。
6. A scanning probe microscopy study of nanostructured TiO2/poly(3-hexylthiophene) hybrid heterojunctions for photovoltaic applications [O] . Laurie Letertre, Roland Roche, Olivier Douhéret, 2018

机译：用于光电应用的纳米结构TiO2 /聚（3-己基噻吩）杂化异质结的扫描探针显微镜研究
7. Molecules on Insulating Films: Scanning-Tunneling Microscopy Imaging of Individual Molecular Orbitals [O] . Repp, Jascha, Meyer, Gerhard, Stojković, Sladjana M., 2005

机译：绝缘膜上的分子：单个分子轨道的扫描隧道显微镜成像。

Multi-scale scanning tunneling microscopy imaging of self-organized regioregular poly(3-hexylthiophene)films

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