首页> 外文期刊>The Journal of Chemical Physics >Supercollisions and energy transfer of highly vibrationally excited molecules
【24h】

Supercollisions and energy transfer of highly vibrationally excited molecules

机译:高振动激发分子的超碰撞和能量转移

获取原文
获取原文并翻译 | 示例
       

摘要

Collisional energy-transfer probability distribution functions of highly vibrationally excited molecules and the existence of supercollisions remain as the outstanding questions in the field of intermolecular energy transfer.In this investigation,collisional interactions between ground state Kr atoms and highly vibrationally excited azulene molecules(4.66 eV internal energy)were examined at a collision energy of 410 cm~(-1)using a crossed molecular beam apparatus and time-sliced ion imaging techniques.A large amount of energy transfer(1000-5000 cm~(-1))in the backward direction was observed.We report the experimental measurement for the shape of the energy-transfer probability distribution function along with a direct observation of supercollisions.
机译:高振动激发分子的碰撞能量转移概率分布函数和超碰撞的存在仍然是分子间能量转移领域的主要问题。在这项研究中,基态Kr原子与高振动激发的z基分子之间的碰撞相互作用(4.66 eV使用交叉分子束装置和时间切片离子成像技术在410 cm〜(-1)的碰撞能量下检查了内部能量),其中大量能量转移(1000-5000 cm〜(-1))我们报告了能量传递概率分布函数形状的实验测量结果以及对超碰撞的直接观察结果。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号