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Singlet-Oxygen Chemiluminescence in Peroxide Reactions

机译:过氧化物反应中的单重态氧化学发光

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摘要

The process of transforming chemical energy into light emission,a phenomenon known as Chemiluminescence(CL),has been an attractive topic of intensive research over the years,in view of its fundamental mechanistic significance and the diversity of practical applications.The in-depth knowledge of chemiluminescent systems paves the way for understanding the otherwise difficult to explore"dark"processes associated with such reactions.This is well illustrated,for instance,by the discovery of the quantum-chain reactions(with and without energy branching)through the detailed elucidation of the CL affiliated with the thermal decomposition of dioxe-tanes.
机译:鉴于化学能的基本机理意义和实际应用的多样性,多年来,化学能转化为光的过程(化学发光现象)一直是深入研究的一个有吸引力的话题。化学发光系统的发展为理解与此类反应相关的否则难以探索的“暗”过程铺平了道路。例如,通过详细的说明发现了量子链反应(带或不带能量支链),就可以很好地说明这一点。 CL的含量与二氧杂环丁烷的热分解有关。

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